• 专利标题:   Making porous graphene membrane comprises oxidizing surface of multilayer graphene, reducing oxidized surface to carry out reductive etching, and repeatedly performing series of the above steps twice until nanopores are formed in graphene.
  • 专利号:   US2018147542-A1, KR2018059135-A, KR1934568-B1, US10245557-B2
  • 发明人:   JHON Y M, JHON Y I, LEE S, YOUNG I J, IN J Y
  • 专利权人:   KOREA INST SCI TECHNOLOGY
  • 国际专利分类:   B01D067/00, B01D071/02, C01B032/194, C01B031/04, C01B032/198, C03C015/00
  • 专利详细信息:   US2018147542-A1 31 May 2018 B01D-067/00 201837 Pages: 16 English
  • 申请详细信息:   US2018147542-A1 US822079 24 Nov 2017
  • 优先权号:   KR158342

▎ 摘  要

NOVELTY - Manufacturing a porous graphene membrane comprises a first step of oxidizing a surface of multilayer graphene, a second step of reducing the oxidized surface of the multilayer graphene to carry out reductive etching of oxidized carbon atoms in a naturally and randomly dispersed form, and a third step of repeatedly performing a series of the first and the second steps at least twice until nanopores are formed in the multilayer graphene. USE - The method is useful for manufacturing a porous graphene membrane (claimed) which is useful in gas and ion separation and seawater desalination. ADVANTAGE - The method: is capable of manufacturing the nanoporous multilayer graphene membrane (having a pore size at an average diameter of less than or equal to 10 nm) in cost effective simplified manner when compared to conventional techniques; easily forms nanopores with a small diameter for polycrystalline multilayer graphene to manufacture a large-area nanoporous graphene membrane since a large-area graphene inevitably possesses grain boundaries; and easily forms nanodefects having a certain depth and/or nanopores penetrating a membrane in multilayer graphene by continuously applying a series of repeated (at least twice) oxidation-reduction processes to a surface of the multilayer graphene membrane, which has not been previously carried out to date.