• 专利标题:   Polymer-modified graphene is obtained by reacting graphene macroinitiator-bromide, N,N,N',N',N"-pentamethyldiethylenetriamine, copper bromide, solvent, atom-transfer-radical-polymerization monomer and water and vacuum drying mixture.
  • 专利号:   CN105153381-A
  • 发明人:   FEI X, LIU X, LUO J, ZHAO F
  • 专利权人:   UNIV JIANGNAN
  • 国际专利分类:   C08F292/00
  • 专利详细信息:   CN105153381-A 16 Dec 2015 C08F-292/00 201637 Pages: 6 English
  • 申请详细信息:   CN105153381-A CN10557350 06 Sep 2015
  • 优先权号:   CN10557350

▎ 摘  要

NOVELTY - A polymer-modified graphene is obtained by adding graphene macroinitiator-bromide, N,N,N',N',N"-pentamethyldiethylenetriamine as ligand, copper bromide, copper, predetermined amount of solvent, atom-transfer-radical-polymerization monomer and water to round bottom flask, freezing and thawing mixture, reacting at 75-90 degrees C for 12-24 hours, processing mixture with membrane filter, washing cake with solvent and ethanol and vacuum drying washed mixture. USE - Polymer-modified graphene (claimed). ADVANTAGE - The polymer-modified graphene has excellent feasibility and universality. DETAILED DESCRIPTION - A polymer-modified graphene is obtained by adding dopamine, 2-bromine-2-methylpropene acyl bromide and triethylamine to beaker, replacing nitrogen to oxygen, stirring mixture in ice-water bath for 8-14 hours, ultrasonically processing homogeneous aqueous dispersion, adding mixture to reaction system, stirring at room temperature for 8-12 hours, centrifuging product, washing product, redispersing solid in deionized water, freeze-drying to obtain graphene macroinitiator-bromide, adding graphene macroinitiator-bromide, N,N,N',N',N"-pentamethyldiethylenetriamine as ligand, copper bromide, copper, predetermined amount of solvent, atom-transfer-radical-polymerization monomer and water to round bottom flask, freezing and thawing mixture, reacting at 75-90 degrees C for 12-24 hours, processing mixture with membrane filter, washing cake with solvent and ethanol and vacuum drying washed mixture.