• 专利标题:   Preparation of cyclic carbonate by adding autoclave with, e.g. epoxy compound and lanthanum-modified graphene catalyst, stirring, dispersing, sealing, vacuumizing, replacing air with carbon dioxide, heating and dissolving in organic solvent.
  • 专利号:   CN108864030-A
  • 发明人:   WANG Q, ZHANG Y
  • 专利权人:   NINGBO HITECH ZONE QUANBAOSHOU NEW MATE
  • 国际专利分类:   B01J023/10, C07D317/36, C07D319/06
  • 专利详细信息:   CN108864030-A 23 Nov 2018 C07D-317/36 201910 Pages: 7 Chinese
  • 申请详细信息:   CN108864030-A CN10964919 23 Aug 2018
  • 优先权号:   CN10964919

▎ 摘  要

NOVELTY - Preparation of cyclic carbonate comprises adding autoclave with 80-100 pts. wt. epoxy compound, 1-5 pts. wt. lanthanum-modified graphene catalyst, 0.05-0.5 pt. wt. 4-dimethylaminopyridine, 0.5-2.8 pts. wt. calcium hydroxyphosphate, 0.6-1.2 pts. wt. cyclodextrin and 0.5-2.8 pts. wt. ammonium bromide, stirring, ultrasonically dispersing for 20-30 minutes, sealing, vacuumizing, replacing air with carbon dioxide for times, keeping pressure at 0.5-5 MPa, and heating to 130-160 degrees C for 3-8 hours; and dissolving in 200-300 pts. wt. organic solvent, filtering off catalyst, washing liquid phase for 3 times with saturated brine, drying with desiccant, and evaporating solvent. USE - Method for preparation of cyclic carbonate. ADVANTAGE - The method does not use heavy metal catalyst, uses lanthanum-modified graphene catalyst which overcomes the quat. ammonium salt which has hard to separate and low activity problems, and has low cost, mild reaction condition, high efficiency, good cycle stability, and no metal pollution problem.