• 专利标题:   Preparation of binder for silicon-based negative electrode of lithium battery, involves adding silicon-based material to maleimide polyurethane solution, cooling, stirring, adding silane coupling agent modified conductive agent and azobisisobutyronitrile, stirring, and reacting.
  • 专利号:   CN115651158-A
  • 发明人:   QIAO P, LI H, ZHAO Z, ZHANG J, ZHANG L
  • 专利权人:   ZHEJIANG DX NEW ENERGY TECHNOLOGY CO LTD
  • 国际专利分类:   C08G018/67, H01M010/0525, H01M004/38, H01M004/48, H01M004/62
  • 专利详细信息:   CN115651158-A 31 Jan 2023 C08G-018/67 202320 Chinese
  • 申请详细信息:   CN115651158-A CN11423088 15 Nov 2022
  • 优先权号:   CN11423088

▎ 摘  要

NOVELTY - Preparation of binder involves: (S1) adding polyurethane prepolymer to a reaction kettle containing N,N-dimethylacetamide as a solvent, stirring until it is completely dissolved, adding dibutyltin dilaurate as a catalyst, heating to 75-90°C, dripping prepared maleimide polyethylene glycol solution into the kettle, and stirring for 2-5 hours to obtain a maleimide polyurethane solution; and (S2) adding silicon-based material containing large number of hydroxyl active groups to the maleimide polyurethane solution, cooling to 50-70°C, continuously stirring for 1-3 hours, adding silane coupling agent modified conductive agent to reaction kettle, adding azobisisobutyronitrile as an initiator, stirring, and reacting for 5-10 hours. USE - Preparation of adhesive for silicon-based negative electrode of lithium battery (claimed). ADVANTAGE - The method provides binder, which can relieve the volume expansion of the silicon-based material and improve the conductivity of the silicon-based material.