• 专利标题:   Three-dimensional composite material for e.g. textile electrodes, comprises woven fabric layer, polymeric film layer obtained by mixing copper microparticles with polyvinyl alcohol solution, and layer made of graphene-based filament.
  • 专利号:   RO135314-A2
  • 发明人:   AILENI R M, CHIRIAC L, TOMA D
  • 专利权人:   INST NAT CERCDEZVOLTARE TEXTILE PIELARI
  • 国际专利分类:   B32B015/04, B32B003/26, B32B033/00
  • 专利详细信息:   RO135314-A2 29 Nov 2021 B32B-015/04 202228 Pages: 1 English
  • 申请详细信息:   RO135314-A2 RO000255 13 May 2020
  • 优先权号:   RO000255

▎ 摘  要

NOVELTY - A three-dimensional (3D) composite material comprises three layers (A1-A3). The layer (A1) is made of a woven fabric support of spun yarns of 100% cotton fibers having a length density of 50x 2 tex in warp, and of spun yarns of 100% cotton fibers having a length density of 50x 3 tex in weft. The density ratio of the two yarn systems is 3.22-3.85. The mass per surface unit of the woven fabric is 410-420 g/m2. The layer (A2) is made of a polymeric film obtained by mixing 15-20 %mass copper microparticles with 80-85 %mass polyvinyl alcohol solution based on distilled water with a mechanical stirrer for 5-8 minutes, and magnetically stirring for 30-40 minutes at 80-90 degrees C. The polyvinyl alcohol solution has a concentration of 99%. The layer (A2) is deposited as a film by scraping or filming on the side of the fabric of the layer (A1), and crosslinking at 150-170 degrees C for 2-5 minutes. The layer (A3) is made of a film obtained by 3D printing by depositing a graphene-based filament. USE - Three-dimensional composite material for manufacturing textile electrodes and flexible sensors for electronics, electrical engineering, medical and textile applications. ADVANTAGE - The composite material has excellent electroconductive properties. DETAILED DESCRIPTION - A three-dimensional (3D) composite material comprises three layers (A1-A3). The layer (A1) is made of a woven fabric support of spun yarns of 100% cotton fibers having a length density of 50x 2 tex in warp, and of spun yarns of 100% cotton fibers having a length density of 50x 3 tex in weft. The density ratio of the two yarn systems is 3.22-3.85. The mass per surface unit of the woven fabric is 410-420 g/m2. The layer (A2) is made of a polymeric film obtained by mixing 15-20 %mass copper microparticles with 80-85 %mass polyvinyl alcohol solution based on distilled water with a mechanical stirrer for 5-8 minutes, and magnetically stirring for 30-40 minutes at 80-90 degrees C. The polyvinyl alcohol solution has a concentration of 99%. The layer (A2) is deposited as a film by scraping or filming on the side of the fabric of the layer (A1), and crosslinking at 150-170 degrees C for 2-5 minutes. The layer (A3) is made of a film obtained by 3D printing by depositing a graphene-based filament directly on the fabric of the layer (A1) on which the polymeric film of the copper-based layer (A2) is deposited.