• 专利标题:   Preparing graphene functionalized nitrile flocking glove comprises adopting water-soluble graphene oxide and organically modified, dispersing in nitrile latex, vulcanization molding at high temperature and thermally reducing.
  • 专利号:   CN108948386-A
  • 发明人:   SHA Y, SHA X, LAN H
  • 专利权人:   NANTONG QS SAFETY PROTECTION TECHNOLOGY
  • 国际专利分类:   C08J005/02, C08L013/02, C08L001/28, C08K013/06, C08K009/04, C08K003/04, C08K003/22, C08K003/06, A41D019/015
  • 专利详细信息:   CN108948386-A 07 Dec 2018 C08J-005/02 201913 Pages: 13 Chinese
  • 申请详细信息:   CN108948386-A CN10351341 17 Apr 2018
  • 优先权号:   CN10351341

▎ 摘  要

NOVELTY - Preparing graphene functionalized nitrile flocking glove comprises (i) mixing calcium nitrate, wetting agent, releasing agent and water, (ii) grinding titanium dioxide, sulfur powder, zinc oxide, zinc dibutyl dithiocarbamate, zinc diethyldithiocarbamate, zinc dimethyl dithiocarbamate, anti-aging agent and dispersing agent, adjusting pH and adding water, (iii) adding auxiliary agent and dispersant to homogeneous dispersion, (iv) taking two parts of nitrile latex, adjusting pH, adding grinding aid, homogeneous graphene dispersion and adding graphene reducing agent, (v) adding color paste to portion of nitrile latex slurry, adding thickener and adjusting viscosity or adding thickener to another nitrile latex slurry and adjusting viscosity, and (vi) picking, washing, brushing, soaking coagulant obtained in step (i), dipping color rubber, solidifying, leaching and dipping primer, cured molding, flocking treating, thermal desorption, chlorine washing, leaching, demolding and post-treating. USE - The method is useful for preparing graphene functionalized nitrile flocking glove. ADVANTAGE - The gloves has 65% mechanical properties, 43 MPa tensile strength, more than 38-360% elongation rate, 100% antibacterial performance, 5 grades of chemical resistance, cutting resistance property and puncture performance. DETAILED DESCRIPTION - Preparing graphene functionalized nitrile flocking glove comprises (i) mixing calcium nitrate, wetting agent, releasing agent and water, where the mass ratio of calcium nitrate, wetting agent, releasing agent and water is (20-30):(0.1-1):(0.1-1):(68-79.8) to obtain latex molding coagulant, (ii) preparing grinding aid for curing and reinforcing latex by mixing 1-4 pts. wt. titanium dioxide, 0.5-1.5 pts. wt. sulfur powder, 1.0-3.0 pts. wt. zinc oxide, 0.1-1 pts. wt. zinc dibutyl dithiocarbamate, 0.1-1 pts. wt. zinc diethyldithiocarbamate, 0.3-1.5 pts. wt. zinc dimethyl dithiocarbamate, 0.1-0.5 pts. wt. anti-aging agent and 0.1-0.5 pts. wt. dispersing agent, adjusting pH by using potassium hydroxide, ammonia or nitrile latex to 8.5-11 and adding deionized water, where the solid content of grinding aid is 40-50%, (iii) adding auxiliary agent for modification treatment and adding dispersant to homogeneous dispersion to obtain homogeneous graphene dispersion, (iv) taking two parts of nitrile latex, adjusting pH value respectively, adding grinding aid in mass ratio of nitrile latex to grinding aid is 100:(3-5), adding homogeneous graphene dispersion, where the mass ratio of graphene to nitrile latex is (0.1-0.5):100 and adding graphene reducing agent, where the mass ratio of graphene reducing agent to graphene of (1-10):1, (v) adding color paste to portion of nitrile latex slurry, adding thickener and adjusting viscosity to 10-200 Mpa/second to obtain color glue and adding thickener to another nitrile latex slurry and adjusting viscosity to 200-500 Mpa/second to obtain primer, and (vi) picking hand mold in sequence, washing with water, washing with alkali, brushing and drying, soaking the coagulant obtained in step (i), drying, dipping the color rubber, solidifying through film, leaching with water, drying and then dipping primer, cured molding, flocking treating, thermal desorption, chlorine washing, leaching, washing, drying, demolding and post-treating.