• 专利标题:   Preparation of graphene-supported palladium-nickel nano-alloy catalyst used for catalytic reduction of nitroaromatics used for preparing aryl amines, involves mixing graphene ethylene glycol slurry and aqueous solution of palladium chloride.
  • 专利号:   CN106423204-A
  • 发明人:   ZHENG G, HAN X, GAO L, FENG X, LI W, FU K, LIU Y
  • 专利权人:   UNIV JINAN
  • 国际专利分类:   B01J023/89, C07C209/36, C07C211/46, C07C211/47, C07C211/52, C07C221/00, C07C223/06, C07C227/04, C07C229/60
  • 专利详细信息:   CN106423204-A 22 Feb 2017 B01J-023/89 201727 Pages: 7 Chinese
  • 申请详细信息:   CN106423204-A CN10857805 28 Sep 2016
  • 优先权号:   CN10857805

▎ 摘  要

NOVELTY - Preparation of graphene-supported palladium-nickel nano-alloy catalyst, involves preparing graphene ethylene glycol slurry and aqueous solution of palladium chloride by Hummers method, stirring and mixing at 25 degrees C for 60 minutes, adding nickel nitrate solid, dissolving sodium glutamate solid, dripping potassium hydroxide in ethylene glycol solution, adjusting pH to 11-13, stirring at 20-25 degrees C, transferring into a water heat kettle, performing hydrothermal reaction at 160 degrees C for 6 hours, washing with water and ethanol, and drying. USE - Preparation of graphene-supported palladium-nickel nano-alloy catalyst used for catalytic reduction of nitroaromatics used for preparing aryl amines (claimed). ADVANTAGE - The graphene-supported palladium-nickel nano-alloy catalyst has excellent catalytic effect, achieves efficient catalysis while reducing the use of palladium and reducing palladium poisoning, and achieves nitroaromatic compounds conversion rate of more than 95%, arylamine selectivity of 98%, and achieves applicability of variety of nitroaromatic compounds. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for method for preparing aryl amines by catalytic reduction of nitroaromatics using graphene-supported palladium-nickel nano-alloy catalyst, which involves adding nitroaromatic compounds and graphene-supported palladium-nickel nano-alloy catalyst in a reaction apparatus in a mass ratio of 20-100:1, adding solvent N,N-dimethylformamide, introducing hydrogen under vacuum conditions at a pressure of 0.3 MPa and heating at 60-100 degrees C for 4-12 hours.