• 专利标题:   Preparation of graphene coated core-shell tin oxide-doped stannous oxide material for anode, involves dissolving graphene oxide and soluble tin salt in water, adding strong base and weak reducing agent, and dispersing in hydrogen peroxide.
  • 专利号:   CN112573508-A
  • 发明人:   CUI D, WU X, LIN L
  • 专利权人:   SHANGHAI NAT ENG RES CENT NANOTECHNOLOGY
  • 国际专利分类:   C01B032/184, C01G019/02, H01M010/0525, H01M004/48, H01M004/62
  • 专利详细信息:   CN112573508-A 30 Mar 2021 C01B-032/184 202138 Pages: 7 Chinese
  • 申请详细信息:   CN112573508-A CN11574684 28 Dec 2020
  • 优先权号:   CN11574684

▎ 摘  要

NOVELTY - Preparation of graphene coated core-shell tin oxide-doped stannous oxide material involves dissolving 40 mg of graphene oxide and 2 mmol of soluble tin salt in 100 mL of deionized water and ultrasonically disperse for 30-60 minutes, and marking as suspension (A), adding 4-6 M strong base to the above solution (A), magnetically stirring uniformly for 10-30 minutes, and marking as suspension (B), adding 1 g of weak reducing agent to the above suspension (B), magnetically stirring for 30-60 minute, centrifuging, and washing with deionized water and ethanol several times to obtain product (C), dispersing product (C) in 100 mL of 15% hydrogen peroxide, magnetically stirring for 6-10 hour, then centrifuging and drying at 60-80 degrees C for 0.5-2 hour to obtain the final product. USE - Preparation of graphene coated core-shell tin oxide-doped stannous oxide material used for anode material for lithium battery (all claimed). ADVANTAGE - The method is environmentally-friendly, and enables preparation of graphene coated core-shell tin oxide-doped stannous oxide material with improved specific capacity during the cycle process of the lithium ion battery, excellent electrochemical performance and reduced energy consumption.