• 专利标题:   Gas molecule detecting composite film, produced by e.g. drawing graphene oxide film on anodic aluminum oxides base film, compounding metal oxide layer or metal layer on surface of graphene oxide base film and placing anodic aluminum oxide.
  • 专利号:   CN108862247-A
  • 发明人:   GAO C, PENG L, LIU Y, GUO Y
  • 专利权人:   HANGZHOU GAOXI TECHNOLOGY CO LTD, UNIV ZHEJIANG
  • 国际专利分类:   C01B032/184
  • 专利详细信息:   CN108862247-A 23 Nov 2018 C01B-032/184 201905 Pages: 12 Chinese
  • 申请详细信息:   CN108862247-A CN10753283 10 Jul 2018
  • 优先权号:   CN10753283

▎ 摘  要

NOVELTY - Gas molecule detecting composite film, produced by e.g. (a) drawing a graphene oxide film on the anodic aluminum oxides (AAO) base film; (b) compounding a metal oxide layer or a metal layer on the surface of the graphene oxide base film to form an ultrathin film; (c) placing the AAO carrying the membrane structure on the surface of the water with the surface of the ultra-thin film facing upward, pressing AAO to sink the AAO, and obtaining a graphene-based ultra-thin film floating on the water surface; (d) lifting the graphene-based ultra-thin film floating on the water surface from the bottom with a silicon substrate, so that the graphene film is laid on the surface of the substrate; (e) evaporating the moisture in the graphene-based ultrathin film at room temperature, freeze drying, and the graphene oxide film is detached from the surface; and (f) reducing the graphene-based ultrathin film, so that its electrical conductivity is greater than 50 S/cm. USE - Used as a gas molecule detecting composite film. ADVANTAGE - The film has: a small thickness and can even reach multiple nanometers; and has extremely high sensitivity. DETAILED DESCRIPTION - Gas molecule detecting composite film, produced by (a) drawing a graphene oxide film on the anodic aluminum oxides (AAO) base film; (b) compounding a metal oxide layer or a metal layer on the surface of the graphene oxide base film to form an ultrathin film; (c) placing the AAO carrying the membrane structure on the surface of the water with the surface of the ultra-thin film facing upward, pressing AAO to sink the AAO, and obtaining a graphene-based ultra-thin film floating on the water surface; (d) lifting the graphene-based ultra-thin film floating on the water surface from the bottom with a silicon substrate, so that the graphene film is laid on the surface of the substrate; (e) evaporating the moisture in the graphene-based ultrathin film at room temperature so that the water content is more than 50 wt.%, the graphene-based ultra-thin film after the evaporation treatment is freeze-dried, and the graphene oxide film is detached from the surface of the silicon wafer; and (f) reducing the graphene-based ultrathin film, so that its electrical conductivity is greater than 50 S/cm.