• 专利标题:   Semiconductive polyolefin composition in power cable, comprises olefin polymer base resin, first carbonaceous structures, carbon black and/or second carbonaceous structures, and optionally additives, where first carbonaceous structures are selected from graphene, and modified graphene.
  • 专利号:   US2023174740-A1, EP4195223-A1
  • 发明人:   THEODORIDIS A, MANIKA G, KADAR R, GKOURMPIS T
  • 专利权人:   BOREALIS AG, BOREALIS AG
  • 国际专利分类:   B32B027/32, C08F010/02, C08F010/06, C08K003/04, H01B001/24, C08K005/00
  • 专利详细信息:   US2023174740-A1 08 Jun 2023 C08K-003/04 202350 English
  • 申请详细信息:   US2023174740-A1 US073854 02 Dec 2022
  • 优先权号:   EP213066

▎ 摘  要

NOVELTY - Semiconductive polyolefin composition comprises 80-99.5 wt.% olefin polymer base resin, 0.1-10.0 wt.% first carbonaceous structures, 0.2-15.0 wt.% carbon black and/or second carbonaceous structures, optionally additives, the semiconductive polyolefin composition has an electrical percolation threshold of 5 wt.% combined amount of components first carbonaceous structures and carbon black and/or second carbonaceous structures dispersed in the olefin polymer base resin, the electrical percolation threshold being defined as the critical concentration in wt.% of the components first carbonaceous structures and carbon black and/or second carbonaceous structures in the olefin polymer base resin, where an exponential increase in electrical conductivity is observed. USE - Semiconductive polyolefin composition used in power cable (claimed). ADVANTAGE - The semiconductive polyolefin composition improves conductivity and processability and increases mechanical characteristics. DETAILED DESCRIPTION - Semiconductive polyolefin composition comprises 80-99.5 wt.% olefin polymer base resin, 0.1-10.0 wt.% first carbonaceous structures, 0.2-15.0 wt.% carbon black and/or second carbonaceous structures, optionally additives, the semiconductive polyolefin composition has an electrical percolation threshold of 5 wt.% combined amount of components first carbonaceous structures and carbon black and/or second carbonaceous structures dispersed in the olefin polymer base resin, the electrical percolation threshold being defined as the critical concentration in wt.% of the components first carbonaceous structures and carbon black and/or second carbonaceous structures in the olefin polymer base resin, where an exponential increase in electrical conductivity is observed, the polyolefin composition has a conductivity of 1* 10-7 S/cm determined according to broadband dielectric spectroscopy for a percolation threshold of 1.0 wt.% or lower and 2-point electrical measurements for a percolation threshold of 1.0 wt.%. INDEPENDENT CLAIMS are included for the following: 1. a power cable, which comprises a semiconductive layer which comprising semiconductive polyolefin composition; and 2. a method for making a power cable, which involves: forming a semiconductive layer around a conductor, where the semiconductive layer is formed from the semiconductive polyolefin composition.