• 专利标题:   Porous carbon material of core-shell structure used in sulfur-carbon composite used in lithium secondary battery, comprises core comprising stack structure of carbon sheets and carbon-containing shell surrounding core.
  • 专利号:   WO2022086211-A1, KR2022054049-A, CN114929619-A, EP4071112-A1, US2023058900-A1, JP2023513164-W
  • 发明人:   JEONG Y, SOHN K, LEE C, JUNG Y C, LI C, SUN Q
  • 专利权人:   LG ENERGY SOLUTION LTD, LG ENERGY SOLUTION LTD, LG ENERGY SOLUTION LTD
  • 国际专利分类:   C01B032/05, H01M010/052, H01M004/36, H01M004/38, H01M004/62, C01B032/318, C01B032/348, H01M004/587, H01M004/60
  • 专利详细信息:   WO2022086211-A1 28 Apr 2022 202240 Pages: 28
  • 申请详细信息:   WO2022086211-A1 WOKR014801 21 Oct 2021
  • 优先权号:   KR138507, CN80008914

▎ 摘  要

NOVELTY - Porous carbon material of a core-shell structure comprises a core comprising a stack structure of carbon sheets, and a carbon-containing shell surrounding the core. USE - The porous carbon material of the core-shell structure is useful in a sulfur-carbon composite used in a lithium secondary battery (claimed). ADVANTAGE - The porous carbon material of the core-shell structure meets the need for a battery system capable of driving electrodes of high loading and low porosity and can significantly improve capacity, charge/discharge, and lifespan characteristics of the lithium ion battery. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) a method for manufacturing the porous carbon material of the core-shell structure involving (a) mixing a carbon precursor having a melting point of 130-350 degrees C with at least one particle chosen from basic zinc carbonazate (BZC), zinc (II) metal oxide-organic framework, and porous structures zinc oxide as a template, (b) heating the mixture to 120-350 degrees C to infiltrate the carbon precursor into the mold, (c) forming a core-shell shape while removing the mold by heating the structure in which the carbon precursor has penetrated into the mold to 600-900 degrees C and (d) heating the core-shell structure at 800-1500 degrees C to vaporize and remove zinc impurities; and (2) a sulfur-carbon composite comprising the porous carbon material and a sulfur component in the core-shell structure.