• 专利标题:   High performance silicon-based lithium ion battery cathode material has core prepared by obtaining silicon-based particle/transition metal composite material, and adding carbon source.
  • 专利号:   CN112993253-A
  • 发明人:   ZHAO H, YANG C, LI Z
  • 专利权人:   UNIV BEIJING SCI TECHNOLOGY
  • 国际专利分类:   B22F009/04, B22F009/06, B82Y030/00, B82Y040/00, C01B032/05, C01B032/21, C01B033/113, C22C030/00, C23C014/18, C23C014/24, C23C016/18, C25D003/02, H01M010/0525, H01M004/38, H01M004/48, H01M004/587, H01M004/62
  • 专利详细信息:   CN112993253-A 18 Jun 2021 H01M-004/62 202167 Pages: 12 Chinese
  • 申请详细信息:   CN112993253-A CN10055605 15 Jan 2021
  • 优先权号:   CN10055605

▎ 摘  要

NOVELTY - The cathode material is a core-shell structure. The core is silicon-based particles/M-carbon composite particles, in which M is a transition metal or its compound. The coating layer is a carbon layer. The core is prepared by obtaining silicon-based particle/M composite material through silicon-based particles and transition metal source, and then adding carbon source for secondary granulation method. USE - Used as high performance silicon-based lithium ion battery cathode material. ADVANTAGE - The inert product produced during the lithium insertion process of the silicon-based material is activated by introducing the substance containing the transition metal element, thus improving the first Coulomb efficiency of the silicon-based material. The process can realize the industrial production of lithium ion batteries with high specific capacity, long cycle life and excellent performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation method of the high performance silicon-based lithium ion battery cathode material comprising (i) taking silicon-based particles and transition metal source as raw material, preparing silicon-based particle/M composite material, as first precursor material; (ii) adding carbon source material and uniformly mixing with the first precursor material; obtaining the silicon-based particles/M-carbon particle as second precursor material by a secondary granulation method; and (iii) coating uniform and continuous carbon layer on the surface of the second precursor material by solid phase sintering or vapor deposition; finally obtaining the silicon-based particle/M-carbon at carbon composite material.