• 专利标题:   Nylon 6 fiber comprises skin-core structure comprising a core layer and a skin layer, skin layer comprises graphene oxide antibacterial agent, and nylon 6 and core layer comprises melamine-based graphene flame retardant and nylon 6.
  • 专利号:   CN108048929-A
  • 发明人:   FANG H, BAO L, WANG G, ZHUO L, WU J, LI T, ZHU E, JIANG X, LI Z, YANG Q, CHEN J, WALTER S T, ROSENHESSLER C, DANESHVA C
  • 专利权人:   FUJIAN HUACAI NEW MATERIAL CO LTD
  • 国际专利分类:   D01D005/34, D01F001/07, D01F001/10, D01F008/12
  • 专利详细信息:   CN108048929-A 18 May 2018 D01F-001/07 201842 Pages: 8 Chinese
  • 申请详细信息:   CN108048929-A CN11471456 29 Dec 2017
  • 优先权号:   CN11471456

▎ 摘  要

NOVELTY - Nylon 6 fiber comprises skin-core structure comprising a core layer and a skin layer, where skin layer comprises a 1-3 wt.% graphene oxide antibacterial agent, and nylon 6. The core layer comprises 5-10 wt.% melamine-based graphene flame retardant, and nylon 6. The preparation of graphene oxide antibacterial agent comprises adding graphene oxide into water and stirring to obtain a graphene oxide suspension with a pH of 8-9, adding a water-soluble polyquaternium salt into the graphene suspension to obtain the first suspension, shaking ultrasonically, cleaning, filtering, and drying. The preparation of melamine-based graphene flame retardant comprises adding graphene oxide into a dimethylformamide solvent, mixing and vortexing to obtain a second suspension, adding second suspension into the melamine-based flame retardant, sonicating, mixing again to obtain a third suspension, heating, refluxing in water bath at 88-92 degrees C for 22-26 hours, cleaning with ethanol, filtering, and drying. USE - Used as nylon 6 fiber. ADVANTAGE - The fiber has excellent antibacterial and flame retardancy, solves problem of poor spinnability and physical and mechanical properties, applies graphene oxide in combination with melamine-based flame retardants and polyquaternium as additives to solve problem of poor dispersion of graphene and improves physical and mechanical properties. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing nylon 6 fiber, comprising (i) mixing graphene oxide antibacterial agent with nylon 6 chips, extruding melting by a twin-screw extruder and mixing at a high speed to obtain a skin-penetratable melt, where amount of graphene oxide antibacterial agent is 1-3 wt.% and nylon 6; (ii) mixing melamine graphene flame retardant with nylon 6 chips, melt-extruding through a twin-screw extruder, mixing at a high speed to obtain a spinnable melt of the core layer, where weight of melamine graphene flame retardant is 5-10%, and nylon 6; and (iii) spinning the skin spinnable melt and the core spinnable melt into the skin core composite assembly, carrying out filament molding, spinning at 230-250 degrees C at 4000-5000 meter/minute, and drafting using drafting device.