• 专利标题:   Preparing tin-based cathode material for lithium-ion based battery with double confinement effect, comprises adding Triton X-100 into sulfur-nitrogen co-doped graphene solution, performing chemical tinning in tin plating solution, filtering, drying, dissolving in water, evaporating and calcining.
  • 专利号:   CN116190587-A
  • 发明人:   ZHANG J, ZHANG Z, OUYANG L, WANG X, LI Y, YANG G
  • 专利权人:   UNIV GUANGXI SCI TECHNOLOGY
  • 国际专利分类:   H01M010/0525, H01M004/36, H01M004/38, H01M004/587, H01M004/62
  • 专利详细信息:   CN116190587-A 30 May 2023 H01M-004/36 202353 Chinese
  • 申请详细信息:   CN116190587-A CN11438345 17 Nov 2022
  • 优先权号:   CN11438345

▎ 摘  要

NOVELTY - Preparing tin-based cathode material for lithium-ion based battery with double confinement effect, comprises (a) taking sodium sulfate, ammonium sulfate or mixture of sodium sulfate and ammonium sulfate, adding distilled water, stirring, (b) dissolving thiourea or cysteine or glycine into solution, stirring, (c) forming two electrode system by platinum electrode and graphite foil, performing electrochemical stripping to prepare sulfur-nitrogen co-doped graphene, (d) filtering the sulfur-nitrogen co-doped graphene, washing with ethanol, (e) adding TritonX-100 (Nonionic surfactant) in the prepared sulfur-nitrogen co-doped graphene solution, performing chemical tinning reaction in the tin plating solution, (f) filtering, drying, (g) dissolving obtained tin/sulfur nitrogen co-doped material graphene in distilled water, dissolving glucose or citric acid or sucrose and/or dopamine in the solution, evaporating distilled water, and (h) calcining dried solid, and cooling to room temperature. USE - The method is useful for preparing tin-based cathode material for lithium-based ion battery with double confinement effect. ADVANTAGE - The method stabilizes the structure of tin, prevents the agglomeration of tin during heat treatment and cycling, improves the electrochemical performance of tin-based composites, has high-performance tin-based anode materials, and promotes the development of new cathode materials for lithium-ion batteries. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for tin-based cathode material for lithium-ion based battery with double confinement effect, which is prepared by above method.