• 专利标题:   Preparing graphene modified glass fiber paper comprises e.g. using centrifuge spraying method or flame spraying method to prepare glass fiber cotton, selecting glass fiber cotton, drying in graphene oxide dispersion and fully immersing.
  • 专利号:   CN109098030-A
  • 发明人:   WANG F
  • 专利权人:   SUQIAN CHINA SOUTHERN AIRLINES NEW MATER
  • 国际专利分类:   D21H013/40, D21H017/00, D21H017/24, D21H017/56, D21H027/00
  • 专利详细信息:   CN109098030-A 28 Dec 2018 D21H-013/40 201913 Pages: 5 Chinese
  • 申请详细信息:   CN109098030-A CN10993616 24 Aug 2018
  • 优先权号:   CN10993616

▎ 摘  要

NOVELTY - Preparing graphene modified glass fiber paper comprises (a) using centrifuge spraying method or a flame spraying method to prepare glass fiber cotton, and the diameter of the fiber is 1-10 mu m; (b) selecting an glass fiber cotton, cutting it and placing it in a cationic surface finishing agent and polyethyleneimine, immersing it in a water bath; (c) placing glass fiber cotton after drying in a graphene oxide dispersion and fully immersing s, rinsing with deionized water, drying, and fully immersing in a chitosan solution, rinsing ande repeating process; (d) reducing the surface of the graphene oxide by drying the glass fiber cotton by ultraviolet curing method to obtain graphene-modified glass fiber cotton; (e) placing graphene-modified glass fiber cotton into a standard fiber fluffer; and (f) adding the stirred graphene-modified glass fiber cotton into a paper machine for papermaking and sufficiently drying to obtain graphene-modified glass fiber paper. USE - The method is useful for preparing graphene modified glass fiber paper. ADVANTAGE - The method can prepare paper having evenly distributed graphene, improved tensile strength, flame retardant properties and hydrophobic performance. DETAILED DESCRIPTION - Preparing graphene modified glass fiber paper comprises (a) using centrifuge spraying method or a flame spraying method to prepare glass fiber cotton, where the fiber length is 5-50 mm and the diameter of the fiber is 1-10 mu m; (b) selecting glass fiber cotton, cutting it and placing it in a cationic surface finishing agent and polyethyleneimine at a concentration of 20-50 g/l, immersing it in a water bath at 50-80 degrees C for 1-2 hours, rinsing with deionized water and allowing to dry at room temperature; (c) placing glass fiber cotton after drying in a graphene oxide dispersion and fully immersing for 1-2 hours, rinsing with deionized water, drying, and fully immersing in a chitosan solution for 1-2 hours, rinsing ande repeating process for 5-10 times; (d) reducing the surface of the graphene oxide by drying the glass fiber cotton by ultraviolet curing method to obtain graphene-modified glass fiber cotton; (e) placing graphene-modified glass fiber cotton into a standard fiber fluffer, setting a rotation speed of 10000-30000 revolutions/minute and stirring for 20-50 minutes; and (f) adding the stirred graphene-modified glass fiber cotton into a paper machine for papermaking and sufficiently drying to obtain graphene-modified glass fiber paper.