• 专利标题:   In-situ preparing triazole-based lubricating oil additives based on friction-click chemistry, comprises e.g. mixing 1-methyl-3-propargyl imidazole ionic liquid, azide compound, nano-copper catalyst and base oil to obtain mixture, performing Husigen-cycloaddition reaction.
  • 专利号:   CN114395432-A, CN114395432-B
  • 发明人:   YU Q, WANG X, XU H, ZHOU F, CAI M
  • 专利权人:   LANZHOU CHEM PHYSICS INST CHINESE ACAD
  • 国际专利分类:   B01J023/72, B01J035/00, B01J035/02, C07D403/04, C07D405/14, C10M133/46, C10N030/06
  • 专利详细信息:   CN114395432-A 26 Apr 2022 C10M-133/46 202285 Chinese
  • 申请详细信息:   CN114395432-A CN10065887 20 Jan 2022
  • 优先权号:   CN10065887

▎ 摘  要

NOVELTY - In-situ preparing triazole-based lubricating oil additives based on friction-click chemistry, comprises (i) mixing 1-methyl-3-propargyl imidazole ionic liquid, azide compound, nano-copper catalyst and base oil to obtain mixture, (ii) applying friction force to the obtained mixture to generate Husigen-cycloaddition reaction to obtain triazole-based lubricating oil additive in the base oil. The Husigen-cycloaddition reaction does not require heating, and the load of friction force is 100-300 N. USE - The method is useful for preparing triazole-based lubricating oil additives based on friction-click chemistry. ADVANTAGE - The method utilizes 1-methyl-3-propargyl imidazole ionic liquid which has relatively large polarity and is easy to be adsorbed on the friction interface.