• 专利标题:   Iron carbide hydrogenation catalyst used for hydrogenating carbon-carbon double bond compound comprises graphene encapsulated iron carbide fixed inside the carbon nanotube.
  • 专利号:   CN105214703-A
  • 发明人:   HOU Z, SHI J, WANG Y, DU W
  • 专利权人:   UNIV ZHEJIANG
  • 国际专利分类:   B01J027/22, C07C013/18, C07C013/26, C07C015/02, C07C015/073, C07C017/354, C07C022/04, C07C029/17, C07C033/20, C07C005/03
  • 专利详细信息:   CN105214703-A 06 Jan 2016 B01J-027/22 201633 Pages: 6 English
  • 申请详细信息:   CN105214703-A CN10651758 10 Oct 2015
  • 优先权号:   CN10651758

▎ 摘  要

NOVELTY - An iron carbide hydrogenation catalyst comprises graphene encapsulated iron carbide fixed inside the carbon nanotube. USE - Iron carbide hydrogenation catalyst used for hydrogenating carbon-carbon double bond compound (claimed). ADVANTAGE - The catalyst has wide source of raw materials, cheap price, simple preparation process, and high activity and reusable stability. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: (1) preparation of iron carbide hydrogenation catalyst comprising (A) mixing glucose, melamine and anhydrous ferric trichloride at mass ratio of 1:1:1 with 1-2 times distilled water to obtain homogeneous mixture, and drying to 80 degrees C for 12 hours to obtain brown solid; (B) grinding, transferring into high-temperature tube furnace, and calcining to 700-800 degrees C for 4 hours under nitrogen atmosphere to obtain black solid; (C) cooling to room temperature, transferring into glass beaker, and washing with 10-20 times 10% hydrochloric acid solution for 6 hours; and (D) filtering through microporous membrane filter, washing with distilled water to neutralize, vacuum-drying to 50 degrees C for 10 hours; and (2) hydrogenation of carbon-carbon double bond compound comprising dispersing hydrogenation catalyst in ethanol solvent, adding into reaction raw materials at mass ratio of 100:1-1:1, filling reactor with hydrogen, heating to 40-100 degrees C at 20 atm, stirring for 20 hours, cooling to room temperature, centrifuging to separate solid catalyst, and distilling reaction solution until 90% or more purity is obtained. The ethanol and reaction raw materials has mass ratio of 200:1-50:1.