• 专利标题:   Graphene oxide modified epoxy resin used as composite material resin matrix, coating, and insulating material in aerospace field, compirses graphene oxide as filler and adds it to epoxy resin matrix to form composite material system, and prepares corresponding graphene oxide-modified epoxy resin.
  • 专利号:   CN116144140-A
  • 发明人:   ZHANG F, WU Z, WEI T, LIU L, MA B, CHANG Y, WANG Q, WANG F, CHEN W, LI J, HUANG Z, BEI Y, LIN P
  • 专利权人:   UNIV CHONGQING, SHANTOU POWER SUPPLY BUREAU GUANGDONG
  • 国际专利分类:   C08J003/205, C08K003/04, C08L063/00
  • 专利详细信息:   CN116144140-A 23 May 2023 C08L-063/00 202353 Chinese
  • 申请详细信息:   CN116144140-A CN10037700 09 Jan 2023
  • 优先权号:   CN10037700

▎ 摘  要

NOVELTY - Graphene oxide modified epoxy resin compirses graphene oxide as filler and adds it to epoxy resin matrix to form a composite material system, and prepares the corresponding graphene oxide-modified epoxy resin. USE - The graphene oxide modified epoxy resin is used as composite material resin matrix, coating, and insulating material in aerospace, mechanical electronics, fresh energy and other fields. ADVANTAGE - The graphene oxide modified epoxy resin: has high mechanical properties, good adhesion, high stability, excellent electrical properties, improved tensile strength and bending strength. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the graphene oxide modified epoxy resin compirsing (1) suspending the helical ribbon in concentrated sulfuric acid, oxidizing with potassium permanganate at 60-90°C at high temperature, obtaining the reaction solution; washing and filtering many times, drying and peeling to obtain graphene oxide; and (2) using a bisphenol A/F diglycidyl ether blend as polymer matrix, adding resin to graphene oxide/acetone suspension, heating and reacting at 50-70°C for 11-13 hours, removing acetone to obtain a dispersion; dispersing a dispersion through graphene nanocomposite obtained by diluting the epoxy resin with three-roll calender to obtain a dispersion; adding the diamine hardener 1,2-diamine cyclohexane into the dispersion, mixing and pouring into the mold for degassing, and solidifying to obtain the graphene oxide modified epoxy resin.