• 专利标题:   Preparation of 2-aminomethyl-4-fluoropyridine-graphene oxide-modified-epoxy resin involves mixing epoxy resin, curing agent, curing accelerator, and additive formed from 2-aminomethyl-4-fluoropyridine, acetonitrile, and graphene oxide.
  • 专利号:   CN111073215-A
  • 发明人:   GE T, XIANG P, ZHANG M, XIE T, SHI Z, ZHANG Y
  • 专利权人:   UNIV SHENYANG CHEM TECHNOLOGY CO LTD
  • 国际专利分类:   C08K003/04, C08K009/04, C08L061/14, C08L063/00
  • 专利详细信息:   CN111073215-A 28 Apr 2020 C08L-063/00 202045 Pages: 6 Chinese
  • 申请详细信息:   CN111073215-A CN11226189 04 Dec 2019
  • 优先权号:   CN11226189

▎ 摘  要

NOVELTY - Preparation of 2-aminomethyl-4-fluoropyridine-graphene oxide-modified-epoxy resin involves adding 1 g graphene oxide (I), 100 ml acetonitrile to the beaker, ultrasonically treating for 3 hours, pouring the shaken mixture into three-necked flask, adding 1 g 2-aminomethyl-4-fluoropyridine (II) with magnetic stirring at 100 degrees C, refluxing for 18 hours, centrifuging and washing 4-6 times under anhydrous ethanol, drying under vacuum at 60 degrees C to obtain amino-methyl-containing additive (III), mixing 100 pts. wt. epoxy resin, 6-10 pts. wt. obtained flame-retardant additive (III), 20-40 pts. wt. flame-retardant and cured compound, 5-8 pts. wt. curing agent, 10-12 pts. wt. modified-phenolic resin, and 1-2 pts. wt. curing accelerator. USE - Preparation of 2-aminomethyl-4-fluoropyridine-graphene oxide-modified-epoxy resin. ADVANTAGE - The method enables preparation of 2-aminomethyl-4-fluoropyridine-graphene oxide-modified-epoxy resin having excellent thermal stability, and mechanical properties. DETAILED DESCRIPTION - Preparation of 2-aminomethyl-4-fluoropyridine-graphene oxide-modified-epoxy resin involves adding 1 g graphene oxide of formula (I), 100 ml acetonitrile to a beaker, ultrasonically treating for 3 hours, pouring the shaken mixture into three-necked flask, adding 1 g 2-aminomethyl-4-fluoropyridine of formula of (II) with magnetic stirring at 100 degrees C, refluxing for 18 hours, centrifuging and washing 4-6 times under anhydrous ethanol, drying under vacuum at 60 degrees C to obtain amino-methyl-containing additive of formula (III), mixing 100 pts. wt. epoxy resin, 6-10 pts. wt. obtained flame-retardant additive (III), 20-40 pts. wt. flame-retardant and cured compound, 5-8 pts. wt. curing agent, 10-12 pts. wt. modified-phenolic resin, and 1-2 pts. wt. curing accelerator. R = group of formula (a).