• 专利标题:   Gas protective composite adsorbent used for protecting sulfur hexafluoride gas and toxic gas derivatives comprises graphene oxide, metal organic framework material, and manganese and cerium-loaded oxidation modified activated carbon.
  • 专利号:   CN111298773-A
  • 发明人:   WEI J, GONG S, WAN T, WU J, XU S, LIU Y, HU X
  • 专利权人:   STATE GRID HUNAN ELECTRIC POWER CO, STATE GRID HUNAN ELECTRIC POWER CO LTD, STATE GRID CORP CHINA
  • 国际专利分类:   B01D053/02, B01J020/22, B01J020/30
  • 专利详细信息:   CN111298773-A 19 Jun 2020 B01J-020/22 202059 Pages: 9 Chinese
  • 申请详细信息:   CN111298773-A CN10238252 30 Mar 2020
  • 优先权号:   CN10238252

▎ 摘  要

NOVELTY - Gas protective composite adsorbent comprises graphene oxide, metal organic framework material, and manganese and cerium-loaded oxidation modified activated carbon. USE - The gas protective composite adsorbent is used for protecting sulfur hexafluoride (SF6) gas and toxic gas derivatives (all claimed). ADVANTAGE - The composite adsorbent has strong adsorbability to SF6 gas and all its toxic gas derivatives, and adsorption efficiency of more than 99.5%. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of gas protective composite adsorbent comprising water washing activated carbon, boiling, drying, adding into mixed solution of nitric acid (HNO3) and hydrogen peroxide (H2O2), heating and stirring at constant temperature, filtering, primary drying, obtaining oxidation modified activated carbon, immersing in potassium permanganate (KMnO4) solution, ultrasonically treating, standing, secondary drying to obtain manganese-loaded oxidation modified activated carbon, immersing in cerium nitrate (Ce(NO3)3) solution, ultrasonically treating for the second time, secondary standing, drying for the third time to obtain manganese and cerium-loaded oxidation modified activated carbon, dissolving manganese and cerium-loaded oxidation modified activated carbon, graphene oxide, copper nitrate hydrate (Cu(NO3)2.2.5H2O) and 1,3,5-benzene tricarboxylic acid in water, ultrasonically stirring, obtaining mixed solution, mixing the mixed solution, N,N-dimethylformamide and ethanol, secondary ultrasonically stirring, heating in oil bath at 80-90 degrees C, reacting, cooling, filtering to obtain solid product, soaking, cleaning and drying.