• 专利标题:   Preparing graphene/nickel complex modified waterborne polyurethane material useful in electromagnetic radiation protection field comprises vacuum-dehydrating, cooling, adding diisocyanate and methyl ethyl ketone, and reacting.
  • 专利号:   CN109053987-A
  • 发明人:   GAO Y, YANG L, CHEN B, JIA T, LI Y, WANG H, ZHANG M
  • 专利权人:   UNIV FUJIAN, FUJIAN POLYTECH TECHNOLOGY CO LTD
  • 国际专利分类:   C08G018/66, C08G018/42, C08G018/48, C08G018/34, C08G018/10, C08K003/04, C08K003/08, C08J005/18
  • 专利详细信息:   CN109053987-A 21 Dec 2018 C08G-018/66 201923 Pages: 6 Chinese
  • 申请详细信息:   CN109053987-A CN10618626 15 Jun 2018
  • 优先权号:   CN10618626

▎ 摘  要

NOVELTY - Preparing graphene/nickel complex modified waterborne polyurethane material comprises placing polyester polyol or polyether polyol in three-necked flask equipped with a thermometer and nitrogen gas protection device, vacuum-dehydrating at 110 degrees C for 2 hours, cooling, adding diisocyanate and methyl ethyl ketone, reacting at 71-85 degrees C for 90-110 minutes to obtain prepolymer, adding methyl ethyl ketone, 2,2-dimethylolpropionic acid (DMPA), and graphene/nickel complex, reacting at 50-90 degrees C for 3 hours, cooling reaction solution to room temperature, adding triethylamine, stirring for 1 hour, pouring reaction solution into deionized water, mechanically stirring for 1 hour to obtain graphene/nickel complex modified aqueous polyurethane emulsion, applying emulsion on release paper without generating bubbles, allowing to stand for 1 days, baking in oven at 80 degrees C for 5 hours, and peeling off from the release paper to obtain film. USE - The graphene/nickel complex modified waterborne polyurethane material is useful in electromagnetic radiation protection field.