• 专利标题:   Method for preparing graphene oxide-modified cellulose acetate forward osmosis membrane for forward osmosis process, involves oscillating and ultrasonic dispersing oxidized graphene, followed by de-foaming and immersing.
  • 专利号:   CN105921034-A
  • 发明人:   LI J, LUN X, MA W, ZHAO L
  • 专利权人:   UNIV BEIJING FORESTRY
  • 国际专利分类:   B01D067/00, B01D069/02, B01D071/02, B01D071/16
  • 专利详细信息:   CN105921034-A 07 Sep 2016 B01D-071/02 201672 Pages: 7 Chinese
  • 申请详细信息:   CN105921034-A CN10453209 21 Jun 2016
  • 优先权号:   CN10453209

▎ 摘  要

NOVELTY - A graphene oxide-modified cellulose acetate forward osmosis membrane preparing method involves oscillating and ultrasonic dispersing oxidized graphene in lactic acid or polyethylene glycol to obtain graphene oxide additive solution. The graphene oxide additive solution is dissolved with cellulose acetate to obtain graphene-modified cellulose acetate permeation film casting solution. The casting solution is de-foamed by allowing standing for 5-12 hours. The resultant solution is immersed in a coagulation bath, which is paved on flat supporting layer to obtain the finished product. USE - Method for preparing a graphene oxide-modified cellulose acetate forward osmosis membrane for forward osmosis process (claimed). ADVANTAGE - The method enables preparing the forward osmosis membrane with better water transfer promoting effect and interception salt rate in an eco-friendly manner. DETAILED DESCRIPTION - A graphene oxide-modified cellulose acetate forward osmosis membrane preparing method involves oscillating and ultrasonic dispersing oxidized graphene in lactic acid or polyethylene glycol at 25-60 degrees c for 0.1-4 hours with ultrasonic frequency of 20-100 kHz to obtain graphene oxide additive solution. The graphene oxide additive solution is dissolved with cellulose acetate at 5-60 degrees C for 12-24 hours until cellulose acetate is fully dissolved to obtain graphene-modified cellulose acetate permeation film casting solution. The permeation film casting solution is de-foamed by allowing to stand for 5-12 hours to make the casting solution completely de-foamed. The resultant solution is immersed in a coagulation bath at 5-30 degrees C for 1-4 hours, which is paved on a flat supporting layer to obtain the finished product. An INDEPENDENT CLAIM is also included for a graphene oxide-modified cellulose acetate forward osmosis membrane.