• 专利标题:   Synthesizing metal-organic framework-magnetic graphene hybrid material by preparing graphene oxide solution and magnetic ferric oxide microspheres, dispersing ferric oxide/polydopamine nanoparticles and adding e.g. S-malic acid.
  • 专利号:   CN107930592-A
  • 发明人:   YU A, DU W, LI Y, ZHANG S, ZHAO W, CHEN S
  • 专利权人:   UNIV ZHENGZHOU
  • 国际专利分类:   B01J020/22, B01J020/20, B01J020/28, B01J020/29, B01J020/30, G01N033/50
  • 专利详细信息:   CN107930592-A 20 Apr 2018 B01J-020/22 201834 Pages: 18 Chinese
  • 申请详细信息:   CN107930592-A CN11257849 04 Dec 2017
  • 优先权号:   CN11257849

▎ 摘  要

NOVELTY - Method for synthesizing metal-organic framework (MOF)-magnetic graphene hybrid material involves (a) preparing graphene oxide solution, (b) preparing magnetic ferric oxide microspheres, (c) self-assembling dopamine on the surface of magnetic ferric oxide microspheres to obtain polydopamine membrane and preparing ferric oxide/polydopamine nanoparticles and (d) synthesizing chiral MOF material, dispersing ferric oxide/polydopamine nanoparticles in graphene oxide solution and adding copper acetate monohydrate, S-malic acid and 4,4'-bipyridine in methanol solution/water. USE - The method is useful for synthesizing MOF-magnetic graphene hybrid material, which is used for rapid selective adsorption of propranolol hydrochloride enantiomers for cytotoxicity in vitro (claimed). ADVANTAGE - The method is simple, and rapidly synthesizes MOF-magnetic graphene hybrid material. The synthesized MOF-magnetic graphene hybrid material has good dispersion, and stable structural properties. DETAILED DESCRIPTION - Method for synthesizing metal-organic framework (MOF)-magnetic graphene hybrid material, involves (a) preparing graphene oxide solution, (b) preparing magnetic ferric oxide microspheres by hydrothermal synthesis, (c) self-assembling dopamine on the surface of magnetic ferric oxide microspheres at room temperature using alkaline buffer solution to obtain polydopamine membrane, and preparing ferric oxide/polydopamine nanoparticles, and (d) synthesizing chiral MOF material using S-malic acid as chiral ligand, dispersing ferric oxide/polydopamine nanoparticles in graphene oxide solution by one-step synthesis method, and gradually adding solution of copper acetate monohydrate, S-malic acid and 4,4'-bipyridine in methanol solution/water.