• 专利标题:   Preparing porous graphene oxide material used as catalyst, comprises preparing graphene oxide sheets, heating graphene oxide suspension containing sheets with base and heating mixture of base-treated graphene oxide sheets and acid.
  • 专利号:   WO2013191654-A1, CA2876930-A1, US2015119581-A1, SG11201408297-A1, US9180442-B2, CA2876930-C, SG11201408297-B
  • 发明人:   LOH K P, SU C L
  • 专利权人:   UNIV SINGAPORE NAT, LOH K P, SU C L
  • 国际专利分类:   B01J021/18, B01J023/00, B82B001/00, B82Y040/00, C01B031/04, B01J023/44, B01J027/20, B01J035/00, C07C211/04, C07C211/28, C07D409/12, B01J023/22, B01J023/40, B01J023/52, B01J023/70, B01J035/10, B01J037/06, B01J037/12, B01J037/34
  • 专利详细信息:   WO2013191654-A1 27 Dec 2013 C01B-031/04 201404 Pages: 25 English
  • 申请详细信息:   WO2013191654-A1 WOSG000249 18 Jun 2013
  • 优先权号:   US660870P, US14407409, CA2876930

▎ 摘  要

NOVELTY - Preparing porous graphene oxide material comprises: (a) preparing graphene oxide sheets from graphite at 40-170 degrees C; (b) providing graphene oxide suspension containing the sheets; (c) heating the suspension with base at 25-300 degrees C for 0.1-48 hours to obtain base-treated graphene oxide sheets; and (d) heating mixture of base-treated graphene oxide sheets and acid at 25-309 degrees C for 0.1-48 hours to get porous graphene oxide material, where weight ratio of base to the sheets and acid to the sheets each has 1:1-50:1, and base in suspension and acid in mixture each has concentration of 0.01-50 N. USE - The method is useful for preparing porous graphene oxide material that is used as catalyst and in oxidation, a reduction, Suzuki coupling, oxygen reduction or an oxidation-reduction tandem reactions (all claimed). ADVANTAGE - The method provides graphene oxide material that is highly magnetic and highly catalytic. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) the porous graphene oxide material having a pore size of 0.2-100 nm, a pore volume of 0.01-5 ml/g, a surface area of 20-2600 m2/g, a carbon/oxygen molar ratio of 2/1-10/1, and a acetate content of 0; and (2) a process of carrying a chemical reaction by agitating a reaction medium containing a reactant or reactants, and a catalyst that is the porous graphene oxide material, where the chemical reaction is an oxidation, a reduction, Suzuki coupling, oxygen reduction or an oxidation-reduction tandem reaction.