• 专利标题:   Composite material used as catalyst in hydrogen evolution reaction of fuel cell, comprises reduced graphene oxide substrate, and ruthenium-molybdenum oxide nanocrystals which comprise ruthenium modified on molybdenum oxide.
  • 专利号:   CN108682873-A, CN108682873-B
  • 发明人:   LIU S, LIU G, CHEN C, ZHENG Q, ZHANG S, GU X
  • 专利权人:   UNIV NANJING XIAOZHUANG
  • 国际专利分类:   H01M004/88, H01M004/90
  • 专利详细信息:   CN108682873-A 19 Oct 2018 H01M-004/90 201901 Pages: 10 Chinese
  • 申请详细信息:   CN108682873-A CN10522836 28 May 2018
  • 优先权号:   CN10522836

▎ 摘  要

NOVELTY - A ruthenium-molybdenum oxide/reduced graphene oxide composite material comprises a reduced graphene oxide substrate and ruthenium-molybdenum oxide nanocrystals provided on the substrate. The ruthenium-molybdenum oxide nanocrystals comprise uniformly compounded ruthenium and molybdenum oxide. The ruthenium is uniformly modified on the surface of molybdenum oxide. USE - Ruthenium-molybdenum oxide/reduced graphene oxide composite material is used as catalyst in hydrogen evolution reaction of fuel cell (claimed). ADVANTAGE - The ruthenium-molybdenum oxide/reduced graphene oxide composite material has excellent hydrogen evolution reaction performance in fuel cell, and is prepared using in-situ growth self-assembly method, by simple process. DETAILED DESCRIPTION - A ruthenium-molybdenum oxide/reduced graphene oxide composite material comprises a reduced graphene oxide substrate and ruthenium-molybdenum oxide (Ru-MoO3-x, where x is 0-3) nanocrystals provided on the substrate. The ruthenium-molybdenum oxide nanocrystals comprise uniformly compounded ruthenium and molybdenum oxide. The ruthenium is uniformly modified on the surface of molybdenum oxide. An INDEPENDENT CLAIM is included for preparation of ruthenium-molybdenum oxide/reduced graphene oxide composite material, which involves dissolving reduced graphene oxide in water, adding polydiallyldimethylammonium chloride (PDDA) solution, surface-modifying, drying, obtaining reduced graphene-PDDA, dissolving reduced graphene-PDDA in water, adding sodium molybdate dihydrate and hexaammineruthenium(III) chloride, stirring, centrifuging, vacuum-drying, and carbonizing.