• 专利标题:   Graphene/boron nitride layered composite material used in super-capacitor, photocatalysis, and adsorption field comprises a film of graphene and boron nitride layers set alternately.
  • 专利号:   CN103570014-A, CN103570014-B
  • 发明人:   CHU Z, HU T, LI Y, JIANG Z, LI G, WANG J, KANG Y
  • 专利权人:   UNIV NAT DEFENSE TECHNOLOGY
  • 国际专利分类:   B82Y030/00, C01B021/064, C01B031/04
  • 专利详细信息:   CN103570014-A 12 Feb 2014 C01B-031/04 201437 Pages: 8 Chinese
  • 申请详细信息:   CN103570014-A CN10568840 15 Nov 2013
  • 优先权号:   CN10568840

▎ 摘  要

NOVELTY - Graphene/boron nitride layered composite material comprises a film of graphene and boron nitride layers set alternately. USE - The composite material is used in super-capacitor, photocatalysis, and adsorption fields. ADVANTAGE - The composite material has specific surface area of 200-800 m2/g, and semiconductor band gap of 0.5-5 eV (claimed); and has uniform thickness, and semiconductor characteristic with adjustable band gap. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing graphene/boron nitride layered composite material, comprising (i) providing boron azine and graphene oxide according to the mass ratio of 1:0.2-5, (ii) mixing boron azine and graphene oxide, adding 50-200 times of anhydrous organic solvent according to graphene oxide quality, ultrasonicating for 60-300 minutes to obtain uniform and stable dispersion of boron azine and graphene oxide mixed solution, (iii) adding boron azine and graphene oxide mixed solution in a culture dish with substrate under the room temperature condition and drying for 60-600 minutes in vacuum, completely removing anhydrous organic solvent to btain layered thin film on the upper substrate, and (iv) transferring layer of thin film into a tubular furnace with the substrate, under the protection of nitrogen, at 500-1500 degrees C under hot condition, processing for 60-180 minutes, naturally cooling to the room temperature to obtain the graphene/boron nitride layered composite material.