• 专利标题:   Macroporous structure based graphene oxide/boric acid-based metal organic framework/polyurethane adsorbents useful for efficient and selective adsorption and separation of aqueous luteolin.
  • 专利号:   CN105664880-A, CN105664880-B
  • 发明人:   LIU S, PAN J, ZHOU Y, ZHU H, YAO Z, YAO J
  • 专利权人:   UNIV JIANGSU, UNIV JIANGSU
  • 国际专利分类:   B01J020/26, B01J020/28, B01J020/30, C07D311/30, C07D311/40
  • 专利详细信息:   CN105664880-A 15 Jun 2016 B01J-020/26 201677 Pages: 14 Chinese
  • 申请详细信息:   CN105664880-A CN10201826 01 Apr 2016
  • 优先权号:   CN10201826

▎ 摘  要

NOVELTY - Macroporous structure based graphene oxide/boric acid-based metal organic framework/polyurethane adsorbents, is claimed. USE - The macroporous structure based graphene oxide/boric acid-based metal organic framework/polyurethane adsorbents is useful for efficient and selective adsorption and separation of aqueous luteolin (LTL) (claimed). ADVANTAGE - The adsorbent has good thermal stability, high adsorption capacity, acid-alkali absorbing/releasing function and significant luteolin (LTL) molecular recognition property (claimed). DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the macroporous structure based graphene oxide/boric acid-based metal organic framework/polyurethane adsorbent comprising (i) preparing graphene oxide; (ii) allowing the growth of graphene oxide on boric acid-based metal organic framework (GOMOF (C)), where the GOMOF (C) is prepared by uniformly mixing graphene oxide, 3-carboxyphenylboronic acid, trimesic acid, zinc nitrate hexahydrate and N,N-dimethylformamide in a reaction kettle, then subjecting to ultrasonic dispersion and washing many times with dimethylformamide solution and vacuum drying, to obtain GOMOF (C); and (iii) preparing graphene oxide/boric acid-based metal organic framework/polyurethane adsorbent (PUGOMOF (C)) by uniformly mixing GOMOF (C) and polyurethane foam, adding absolute ethanol in a reaction flask, subjecting to ultrasonic dispersion and stirring uniformly and washing many times with ethanol and vacuum drying, to obtain PUGOMOF (C).