• 专利标题:   Synthesis of three-dimensional cobalt carbonate quantum dot-coated graphene composite electrode material involves adding oleic acid to ethanol solution, adding cobalt salt and graphene oxide and hydrothermally reacting suspension.
  • 专利号:   CN107331835-A
  • 发明人:   CAO L, KANG Q, LI J, HUANG J, CHENG Y
  • 专利权人:   UNIV SHAANXI SCI TECHNOLOGY
  • 国际专利分类:   B82Y030/00, H01M010/0525, H01M010/054, H01M004/36, H01M004/58, H01M004/62
  • 专利详细信息:   CN107331835-A 07 Nov 2017 H01M-004/36 201783 Pages: 12 Chinese
  • 申请详细信息:   CN107331835-A CN10428793 08 Jun 2017
  • 优先权号:   CN10428793

▎ 摘  要

NOVELTY - Oleic acid is added to ethanol solution, to obtain solution (a). A cobalt salt and a precipitant are added to solution (a) and stirred, to obtain solution (b). Graphene oxide is added to solution (b) and stirred, to obtain suspension (c). The suspension (c) is ultrasonically processed, and homogeneously hydrothermally reacted, to obtain precipitate. The precipitate is separated, washed and dried, to obtain three-dimensional cobalt carbonate quantum dot-coated graphene composite electrode material. USE - One-step solvothermal synthesis of three-dimensional cobalt carbonate quantum dot-coated graphene composite electrode material (claimed). ADVANTAGE - The method provides three-dimensional cobalt carbonate quantum dot-coated graphene composite electrode material with excellent mechanical strength, stability, charging and discharging characteristics and electrochemical characteristics. DETAILED DESCRIPTION - Oleic acid is added to ethanol solution such that the volume ratio of oleic acid and ethanol solution is (0.5-3):70, to obtain solution (a). A cobalt salt and a precipitant are added to solution (a) and stirred, to obtain solution (b). The volume ratio of cobalt salt and ethanol solution is (2-6) mmol:70 mL. Graphene oxide is added to solution (b) and stirred, to obtain suspension (c). The volume ratio of graphene oxide and ethanol solution is (0.07-0.14) g:70 mL. The suspension (c) is ultrasonically processed, and homogeneously hydrothermally reacted, to obtain precipitate. The precipitate is separated, washed and dried, to obtain three-dimensional cobalt carbonate quantum dot-coated graphene composite electrode material.