• 专利标题:   Preparing porous composite material used in lithium ion battery, by treating graphene oxide with water, adding manganese source, sulfur source and urea to graphene oxide suspension, magnetically stirring, drying, washing and vacuum-drying.
  • 专利号:   CN108365185-A
  • 发明人:   CHEN Z, HU Z, LUO Z, LI Q, CHEN D
  • 专利权人:   UNIV SHANGHAI
  • 国际专利分类:   H01M004/36, H01M004/58, H01M004/62, H01M010/0525
  • 专利详细信息:   CN108365185-A 03 Aug 2018 H01M-004/36 201862 Pages: 10 Chinese
  • 申请详细信息:   CN108365185-A CN10017807 09 Jan 2018
  • 优先权号:   CN10017807

▎ 摘  要

NOVELTY - The method for preparing porous manganese sulfide and graphene composite material involves (a) adding 10-50 ml graphene oxide having a concentration of 5-10 mg/ml to 100-200 ml distilled water and ultrasonically treating at a power of 45 W in an ultrasonic machine for 1-3 hours to obtain a uniform graphene oxide suspension, (b) adding 3-5 g manganese source, 2-5 g sulfur source and 0.2-1 g urea to suspension, placing the mixed solution on a double-display thermostatic magnetic stirrer and magnetically stirring for 0.5 hour to obtain an uniform mixture, (c) transferring the mixture to a reaction kettle, drying at 160-200 degrees C for 24 hours, cooling to room temperature, washing 3 times with water and ethanol and vacuum-drying at 80 degrees C overnight to obtain a black solid powder, and (d) placing the solid powder in a tube furnace and calcining at a temperature of 300-500 degrees C and heating rate of 3 degrees C/minute under nitrogen conditions for 4 hours. USE - Method is useful for preparing porous manganese sulfide and graphene composite material, which is useful in lithium ion battery. ADVANTAGE - The composite material has excellent electrical conductivity and structural stability, and improves charge and discharge characteristics, cycle stability and rate performance of the lithium ion battery.