• 专利标题:   Catalyst comprises components comprising MCM-22 molecular sieve and metal oxide comprising manganese oxide, manganese chromium compound, manganese aluminum compound, manganese zirconium compound, manganese indium compound, zinc oxide compound, zinc chromium compound and cobalt aluminum compound.
  • 专利号:   CN112973775-A, CN112973775-B
  • 发明人:   JIAO F, FENG J, PAN X, BAO X
  • 专利权人:   CAS DALIAN CHEM PHYSICAL INST
  • 国际专利分类:   B01J029/70, B01J029/74, B01J029/76, B01J029/78, C10G002/00
  • 专利详细信息:   CN112973775-A 18 Jun 2021 B01J-029/70 202163 Pages: 16 Chinese
  • 申请详细信息:   CN112973775-A CN11289566 14 Dec 2019
  • 优先权号:   CN11289566

▎ 摘  要

NOVELTY - Catalyst comprises component (I) and component (II), where the components (A) and (B) are compounded together in a mechanical mixing manner. The component (A) is metal oxide. The component (B) is MCM-22 molecular sieve. The metal oxide comprises a manganese oxide compound (I), a manganese chromium compound (II), a manganese aluminum compound (III), a manganese zirconium compound (IV), a manganese indium compound (V), a zinc oxide compound (VI), a zinc chromium compound (VII), a zinc aluminum compound (VIII), a zinc gallium compound (IX), a zinc indium compound (X), a cerium oxides compound (XI), a cobalt aluminum compound (XII), a gallium oxide compound (XIII), a bismuth oxide compound (XIV), an indium oxide compound (XV), an indium aluminum manganese compound (XVI), and/or an indium gallium manganese compound (XVII). USE - Catalyst. ADVANTAGE - The catalyst has high product yield and selectivity, and selectivity of liquid fuel in C5C11 of 5080%, selectivity of aromatic hydrocarbon in C5C11 of lower than 40%, and selectivity of by-product methane of lower than 8%. DETAILED DESCRIPTION - Catalyst comprises component (I) and component (II), where the components (A) and (B) are compounded together in a mechanical mixing manner. The component (A) is metal oxide. The component (B) is MCM-22 molecular sieve. The metal oxide comprises a manganese oxide compound of formula: MnOx (I), a manganese chromium compound of formula: MnaCr(1-a)Ox (II), a manganese aluminum compound of formula: MnaAl(1-a)Ox (III), a manganese zirconium compound of formula: MnaZr(1-a)Ox (IV), a manganese indium compound of formula: MnaIn(1-a)Ox (V), a zinc oxide compound of formula: ZnOx (VI), a zinc chromium compound of formula: ZnaCr(1-a)Ox (VII), a zinc aluminum compound of formula: ZnaAl(1-a)Ox (VIII), a zinc gallium compound of formula: ZnaGa(1-a)Ox (IX), a zinc indium compound of formula: ZnaIn(1-a)Ox (X), a cerium oxides compound of formula: CeOx (XI), a cobalt aluminum compound of formula: CoaAl(1-a)Ox (XII), a gallium oxide compound of formula: GaOx (XIII), a bismuth oxide compound of formula: BiOx (XIV), an indium oxide compound of formula: InOx (XV), an indium aluminum manganese compound of formula: InaAl-bMn(1-ab)Ox (XVI), and/or an indium gallium manganese compound of formula: InaGabMn(1-ab)Ox (XVII). The specific surface area of compounds (I), (VI), (XI), (XIII), (XIV)and (XV) are 1-100 m2/g, preferably 50-100 m2/g. The specific surface area of compounds (II), (III), (IV), (V), (VII), (VIII), (IX), (X), (XII), (XVI), and (XVII) are 5-150 m2/g, preferably 50-150 m2/g. The specific surface area of micropores in the MCM-22 molecular sieve accounts for 70-100% of the total specific surface area of the molecular sieve. x = 0.7-3.7; a = 0-1;and a+b = 0-1. An INDEPENDENT CLAIM is included for a method for direct conversion of syngas to liquid fuel, involving using syngas as reaction raw material to carry out the conversion reaction in a fixed bed or a moving bed, and using the catalyst.