• 专利标题:   Metal oxide/graphene composite catalyst includes metal oxide as copper-zinc-aluminum mixed metal oxide, and is uniformly dispersed on reduced graphene oxide in layered hydrotalcite structure.
  • 专利号:   CN111905749-A
  • 发明人:   LUO J, CHEN X, SUN C, FENG M, JIANG C, HE M
  • 专利权人:   YANCHENG INST TECHNOLOGY
  • 国际专利分类:   B01J023/80, B01J035/10, C07C029/154, C07C031/04
  • 专利详细信息:   CN111905749-A 10 Nov 2020 B01J-023/80 202101 Pages: 9 Chinese
  • 申请详细信息:   CN111905749-A CN10859565 24 Aug 2020
  • 优先权号:   CN10859565

▎ 摘  要

NOVELTY - Metal oxide/graphene composite catalyst includes metal oxide as copper-zinc-aluminum mixed metal oxide, and is uniformly dispersed on the reduced graphene oxide in a layered hydrotalcite structure. USE - Metal oxide/graphene composite catalyst. ADVANTAGE - The metal oxide/graphene composite catalyst can effectively solve the problems of easy deactivation of the existing catalyst, low carbon dioxide conversion rate and low formaldehyde selectivity. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing metal oxide/graphene composite catalyst, which involves: (A) adding freeze-dried graphene oxide to a mixed solution of ethanol and water to obtain solution A after ultrasonic treatment; (B) dissolving copper (II) nitrate trihydrate, zinc nitrate hexahydrate and aluminum nitrate nonahydrate in water to obtain solution B; (C) dissolving sedum hydroxide and sodium carbonate in water to obtain solution C; (D) adding solution B and solution C to solution A; (E) transferring the resulting mixed solution into the reaction vessel under sealing and heating; (F) cooling the reaction vessel to room temperature; (G) filtering the resulting solution by using absolute ethanol and water to obtain composite of copper-zinc-aluminum hydrotalcite and reduced graphene oxide; (H) roasting the obtained composite in a reaction vessel under protection of inert gas; and (I) naturally cooling at room temperature to obtain the composite of copper-zinc-aluminum mixed metal oxide and reduced graphene oxide.