• 专利标题:   Ternary cathode composite material used in lithium ion batteries comprises shell coated on surface of core including first coating e.g. graphene or carbon nanotube composite and second coating e.g. carbonized product of polyvinyl alcohol.
  • 专利号:   CN111092210-A
  • 发明人:   TAN Q, XU Y
  • 专利权人:   CAS LANGFANG PROCESS ENG INST, INST PROCESS ENG CHINESE ACAD SCI
  • 国际专利分类:   C01B032/182, H01M010/0525, H01M004/36, H01M004/485, H01M004/505, H01M004/525, H01M004/60, H01M004/62
  • 专利详细信息:   CN111092210-A 01 May 2020 H01M-004/36 202044 Pages: 15 Chinese
  • 申请详细信息:   CN111092210-A CN11400301 30 Dec 2019
  • 优先权号:   CN11400301

▎ 摘  要

NOVELTY - Ternary cathode composite material comprises a shell coated on the surface of a core including first coating and second coating, where the first coating is a 3D nano-network layered structure having a conductive polymer, graphene or carbon nanotube composite and a hydrogen-containing lithium titanium oxide compound and open-framework iron fluoride dispersed in situ on the surface of the composite and the second coating is a carbonized product of polyvinyl alcohol. USE - The composite material is useful in lithium ion batteries (claimed). ADVANTAGE - The lithium ion battery: has high ion conductivity and electronic conductivity; ensures outstanding advantages e.g. specific discharge capacity, first-time Coulombic efficiency and good cycle stability. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing ternary cathode composite material comprises (i) dissolving polyvinyl alcohol in solvent to obtain solution A, (ii) adding first coating into solution A and mixing uniformly to obtain solution B, (iii) adding ternary cathode material into solution B to obtain slurry C and (iv) carrying out microwave treatment on slurry C at 300-500 degrees C to obtain the product.