• 专利标题:   Preparing polyimide composite material involves dispersing graphene oxide and carbon nanotubes uniformly in water to obtain blending dispersion of carbon nanotubes/graphene oxide, adding dopamine hydrochloride, adjusting pH value.
  • 专利号:   CN108276577-A
  • 发明人:   SHI H, ZHANG Y, WANG H, MAO H
  • 专利权人:   UNIV TIANJIN POLYTECHNIC
  • 国际专利分类:   C08G073/10, C08J005/18, C08K003/04, C08K007/24, C08K009/04
  • 专利详细信息:   CN108276577-A 13 Jul 2018 C08G-073/10 201853 Pages: 9 Chinese
  • 申请详细信息:   CN108276577-A CN10105449 02 Feb 2018
  • 优先权号:   CN10105449

▎ 摘  要

NOVELTY - Preparing a polyimide composite material involves dispersing graphene oxide and carbon nanotubes uniformly in water to obtain a blending dispersion of carbon nanotubes/graphene oxide, adding dopamine hydrochloride, adjusting the pH value to 7.5-10.5, and complet reacting until the reaction to obtain mixture product. The obtained mixture product is washing and drying to obtain polydopamine-modified carbon nanotube graphene. The polydopamine-modified carbon nanotube graphene, dianhydride and diamine is add to an aprotic polar solvent, and performing in-situ polymerization under nitrogen protection, stirring at 10-30 degrees C to obtain polydopamine as modified carbon nanotube graphene/polyamic acid precursor solution. The aprotic polar solvent is N,N-dimethylformamide, N,N-dimethylacetamide, dimethyl sulfoxide or N-methylpyrrolidone. USE - Method for preparing a polyimide composite material. ADVANTAGE - The method enables to prepare a polyimide composite material, which has simple technique, green and safe, convenient for industrial production. DETAILED DESCRIPTION - The polydopamine-modified carbon nanotube graphene/polyamic acid precursor solution is formed into a desired form by casting, a mold or other composite material, and is cured at 40-100 degrees C, and then at 100 degrees and mixture is incubated at 450 degrees C for 1-4 hours to obtain a polyimide composite.