• 专利标题:   Preparation of reclaimed rubber/nitrile rubber composite adhesive, involves mixing poly(oxyethylene), graphene oxide, catalyst, reacting, filtering, filtrate with poly(vinyl chloride), reclaimed rubber and nitrile rubber & vulcanizing.
  • 专利号:   CN107312214-A
  • 发明人:   TANG F, WANG P, RUI G, ZHOU H, DAI X, ZHANG J
  • 专利权人:   ANHUI SHIJIECUN NEW MATERIALS CO LTD
  • 国际专利分类:   C08K013/02, C08K003/04, C08K003/30, C08K005/098, C08L017/00, C08L027/06, C08L071/02, C08L009/02
  • 专利详细信息:   CN107312214-A 03 Nov 2017 C08L-009/02 201803 Pages: 5 Chinese
  • 申请详细信息:   CN107312214-A CN10451225 15 Jun 2017
  • 优先权号:   CN10451225

▎ 摘  要

NOVELTY - Preparation of reclaimed rubber/nitrile rubber composite adhesive, involves adding poly(ethylene glycol), graphene oxide and molybdenum disulfide to water, dispersing, freeze-drying to obtain powder, mixing obtained powder with anhydride, catalyst and dimethyl sulfoxide, placing in an oil bath, reacting, separating, washing obtained product with acetone, filtering, drying, mixing with poly(vinyl chloride), reclaimed rubber, nitrile rubber, zinc phthalate, sulfur and stearate, kneading using open roll mill, cooling kneaded product, placing in flat vulcanizing machine and molding. USE - Preparation of reclaimed rubber/nitrile rubber composite adhesive (claimed). ADVANTAGE - The method enables preparation of reclaimed rubber/nitrile rubber composite adhesive with high strength, excellent abrasion resistance, aging resistance, corrosion resistance, compatibility, bonding strength and stability. DETAILED DESCRIPTION - Preparation of reclaimed rubber/nitrile rubber composite adhesive, involves adding poly(ethylene glycol), graphene oxide and molybdenum disulfide to water, stirring at high-speed for 30-40 minutes, dispersing ultrasonically for 25-28 minutes, freeze-drying to obtain powder, mixing obtained powder with succinic anhydride, phthalic anhydride, catalyst and dimethyl sulfoxide, placing in an oil bath, reacting for 3-3.5 hours, separating, washing obtained product with acetone, filtering, drying filtrate, mixing with poly(vinyl chloride), placing in open roll mill, kneading (I) to obtain modified poly(vinyl chloride), mixing reclaimed rubber, nitrile rubber, zinc phthalate, tribasic lead sulfate, barium stearate and zinc stearate, kneading using open roll mill for 2-3 minutes at 160-165 degrees C, adding modified poly(vinyl chloride) and sublimed sulfur, kneading (II) for 5-6 minutes, cooling to room temperature, keep aside for 24-26 hours at room temperature, placing in flat vulcanizing machine and molding. The mass ratio of poly(ethylene glycol), water, graphene oxide and molybdenum disulfide is 1-1.2:30-35:5-5.3:0.3-0.4. The mass ratio of powder, succinic anhydride, phthalic anhydride, catalyst and dimethyl sulfoxide is 9-11:1-1.3:5-5.5:0.8-0.9:19-21.