• 专利标题:   Preparing geraniol-graphene oxide sustained-release thermally conductive smoke composite material, by introducing material made of e.g. geraniol and graphene oxide into reaction kettle for reacting, washing product, filtering and drying.
  • 专利号:   CN111743192-A
  • 发明人:   YU S, YAO J, LI D, YANG X, YUE X, WANG W
  • 专利权人:   CHINA TOBACCO HUBEI IND LLC, HUBEI XINYE RECONSTITUTED TOBACCO DEV CO
  • 国际专利分类:   A24B003/14, C01B032/198
  • 专利详细信息:   CN111743192-A 09 Oct 2020 A24B-003/14 202090 Pages: 12 Chinese
  • 申请详细信息:   CN111743192-A CN10662718 10 Jul 2020
  • 优先权号:   CN10662718

▎ 摘  要

NOVELTY - Preparation of geraniol-graphene oxide sustained-release thermally conductive smoke composite material involves: (S1) adding graphite powder to a pre-oxidation system for pre-oxidation, diluting after reaction is completed, carrying out suction filtration, washing until neutral, and naturally drying to obtain a pre-oxidized graphite powder; (S2) taking concentrated sulfuric acid, putting into an ice bath for cooling, mixing the pre-oxidized graphite powder and sodium nitrate, adding to the concentrated sulfuric acid in the ice bath, slowly adding potassium permanganate, ultrasonically processing, and reacting to obtain a mixed system (A); and (S3) subjecting the mixed system (A) to a water bath reaction under ultrasonic conditions, adding deionized water to stop the reaction after the water bath reaction is completed, then adding hydrogen peroxide, reacting, and adding the hydrochloric acid solution to dissolve to obtain a mixed system (B). USE - The method is useful for preparing geraniol-graphene oxide sustained-release thermally conductive smoke composite material. ADVANTAGE - The method provides geraniol-graphene oxide sustained-release thermally conductive smoke composite material with high thermal conductivity. DETAILED DESCRIPTION - Preparation of geraniol-graphene oxide sustained-release thermally conductive smoke composite material involves: (S1) adding graphite powder to a pre-oxidation system for pre-oxidation, diluting after reaction is completed, carrying out suction filtration, washing until neutral, and naturally drying to obtain a pre-oxidized graphite powder; (S2) taking concentrated sulfuric acid, putting into an ice bath for cooling, mixing the pre-oxidized graphite powder and sodium nitrate, adding to the concentrated sulfuric acid in the ice bath, slowly adding potassium permanganate, ultrasonically processing, and reacting to obtain a mixed system (A); (S3) subjecting the mixed system (A) to a water bath reaction under ultrasonic conditions, adding deionized water to stop the reaction after the water bath reaction is completed, then adding hydrogen peroxide, reacting, and adding the hydrochloric acid solution to dissolve to obtain a mixed system (B); (S4) removing the excess acid and by-products in the mixed system (B) to obtain graphite oxide, then subjecting to washing, ultrasonically processing, centrifuging and drying subsequent treatment to obtain graphene oxide; (S5) dissolving geraniol in absolute ethanol, thoroughly mixing by magnetic stirring, adding graphene oxide, ultrasonically processing to obtain a precursor of solvothermal reaction, and continuously stirring to obtain a material; and (S6) introducing the material into a reaction kettle, tightly tightening the reaction kettle, placing in an oven for reacting, taking out the reaction product after the reaction is completed, washing with absolute ethanol, filtering, vacuum drying, grinding and sealing to obtain a tobacco material.