• 专利标题:   Aerogel used in supercapacitor, is prepared by crosslinking mixture of polyamic acid and graphene oxide with cobalt salt, and carbonizing.
  • 专利号:   CN110642250-A
  • 发明人:   FAN W, WANG D, LIU T, YUAN S
  • 专利权人:   UNIV DONGHUA
  • 国际专利分类:   B01J013/00, C01B032/05, C01B032/184, C01B032/348
  • 专利详细信息:   CN110642250-A 03 Jan 2020 C01B-032/348 202007 Pages: 9 Chinese
  • 申请详细信息:   CN110642250-A CN10863719 12 Sep 2019
  • 优先权号:   CN10863719

▎ 摘  要

NOVELTY - Aerogel is prepared by crosslinking mixture of polyamic acid and graphene oxide with cobalt salt and carbonizing to obtain the product. USE - The aerogel is used in supercapacitor (claimed). ADVANTAGE - The aerogel has high specific capacity and excellent rate performance, and is simple to process and operate. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing the aerogel involving (i) dissolving aqueous-soluble polyamic acid in aqueous graphene oxide solution and stirring to obtain graphene oxide/polyamic acid hydrogel solution, (ii) adding graphene oxide/polyamic acid hydrogel solution obtained in step (i) to cobalt salt solution, stirring to obtain cobalt salt/graphene oxide/polyamic acid hydrogel, where the mass ratio of the cobalt salt to aqueous-soluble polyamic acid in step (i) is 0-0.3, and the mass ratio is not 0, (iii) freezing the cobalt salt/graphene oxide/polyamic acid hydrogel in liquid nitrogen, freeze-drying to obtain cobalt salt/ graphene oxide/polyamic acid aerogel, and (iv) performing imidization process on cobalt salt/graphene oxide/polyamic acid aerogel, and carbonizing to obtain the product.