• 专利标题:   Preparing graphene-aluminum composite material useful in combustion, comprises e.g. adding concentrated sulfuric acid, potassium permanganate, sodium nitrate, and graphite into beaker, adding hydrogen peroxide, ultrasonically dispersing, adding aluminum powder and hydrazine hydrate, and heating.
  • 专利号:   CN115304438-A
  • 发明人:   CHEN B, LIU Q, HUANG J, LI D, DING X
  • 专利权人:   UNIV SICHUAN SCI ENGINEERING
  • 国际专利分类:   B22F001/16, C06B027/00
  • 专利详细信息:   CN115304438-A 08 Nov 2022 C06B-027/00 202309 Chinese
  • 申请详细信息:   CN115304438-A CN10977153 15 Aug 2022
  • 优先权号:   CN10977153

▎ 摘  要

NOVELTY - Preparing graphene-aluminum composite material, comprises adding concentrated sulfuric acid, potassium permanganate, sodium nitrate, and graphite into beaker under an ice-water bath, stirring and dissolving, and placing in a sealed container, then adding deionized water, heating the system, and stirring and reacting, adding hydrogen peroxide, and filtering and washing, and placing graphene oxide slurry in a beaker, adding deionized water, ultrasonically dispersing, and maintaining in an ultrasonic state, placing spare aluminum powder in a three-necked flask, adding ethanol, then dropwise adding hydrazine hydrate, and heating to refluxing, adding graphene oxide dispersion into a three-necked flask, reflux stirring, filtering to obtain crude product, washing with ethanol, and drying to obtain final product. USE - The graphene-aluminum composite material is useful in combustion (claimed). ADVANTAGE - The material: has tightly coated graphene, which changes the shape of aluminum powder to a certain extent, increases the distance between aluminum particles, and improves storage reliability; increases the combustion efficiency of 20% due to coating and dispersion of graphene, which makes the aluminum powder react more completely; and deduces the combustion mechanism from the combustion products. DETAILED DESCRIPTION - Preparing graphene-aluminum composite material, comprises (1) adding concentrated sulfuric acid, potassium permanganate, sodium nitrate, and graphite into a beaker under an ice-water bath, stirring and dissolving, and placing in a sealed container for 24 hours, stirring at 35 ℃ for 30 minutes, then slowly adding 500 ml deionized water, slowly heating the system at 100 ℃, and stirring and reacting at 100 ℃ for 15 minutes, dropwise adding hydrogen peroxide, and filtering and washing to obtain graphene oxide slurry, and (2) (2a) placing the graphene oxide slurry in a beaker, adding deionized water, and then ultrasonically dispersing at 45 ℃ to obtain uniformly dispersed graphene oxide dispersion, and maintaining in an ultrasonic state, (2b) placing spare aluminum powder in a three-necked flask, adding ethanol, then dropwise adding hydrazine hydrate, and heating and refluxing, and (2c) heating the system at 90-95 ℃, slowly adding the graphene oxide dispersion obtained in step (2a) into a three-necked flask for 30 minutes, reflux stirring, and filtering to obtain crude product, washing for many times with ethanol, and drying in a vacuum oven to obtain final product.