• 专利标题:   Manufacturing graphene sheet used for e.g. LCD, comprises adding sulfuric acid solution and nitric acid solution in graphite and then stirring to obtain mixture, and adding oxidizing agent in the mixture and then stirring and neutralizing.
  • 专利号:   KR1362349-B1
  • 发明人:   JONG S Y, SU H L
  • 专利权人:   VASTEEM CO LTD, SU H L
  • 国际专利分类:   B01J006/00, C01B031/02
  • 专利详细信息:   KR1362349-B1 13 Feb 2014 C01B-031/02 201418 Pages: 20
  • 申请详细信息:   KR1362349-B1 KR094534 28 Aug 2012
  • 优先权号:   KR094534

▎ 摘  要

NOVELTY - The method comprises: adding sulfuric acid solution and nitric acid solution in graphite and then stirring for 24 hours to obtain a graphite-acid mixture; adding an oxidizing agent in the mixture at below 20 degrees C; stirring the mixture for 72 hours; neutralizing the mixture by washing with distilled water; vacuum drying the mixture at 80 degrees C to generate a graphite oxide; and performing heat treatment on the graphite oxide at 700-2000 degrees C in an argon gas atmosphere for 5 minutes and then carrying out oxidation-reduction reaction to obtain a graphene sheet. USE - The method is useful for manufacturing a graphene sheet (claimed) that is useful for a display device such as plasma display panel, LED, LCD, cold-cathode fluorescent lamps and flat fluorescent lamp and electronic and electric devices. ADVANTAGE - The method allows economical manufacture of the ultra thin graphene sheet with high quality and thermal conductivity. DETAILED DESCRIPTION - The method comprises: adding sulfuric acid solution and nitric acid solution in graphite and then stirring for 24 hours to obtain a graphite-acid mixture; adding an oxidizing agent in the mixture at below 20 degrees C; stirring the mixture for 72 hours; neutralizing the mixture by washing with distilled water; vacuum drying the mixture at 80 degrees C to generate a graphite oxide; and performing heat treatment on the graphite oxide at 700-2000 degrees C in an argon gas atmosphere for 5 minutes and then carrying out oxidation-reduction reaction to obtain a graphene sheet. A mass ratio of the sulfuric acid solution and the nitric acid solution is 7:3. The graphene sheet has thermal conductivity of 700-2000 W/mk.