• 专利标题:   Preparation of graphene-based heat and moisture exchange composite film used in membrane type heat exchange system, involves depositing graphene quantum dots and metal organic framework on polyester microporous membrane, and drying.
  • 专利号:   CN110551318-A
  • 发明人:   ZHANG Y, DUAN Y, ZHAO Z
  • 专利权人:   SHANGHAI LEVSON NANOTECHNOLOGY CO LTD
  • 国际专利分类:   C08J009/36, C08J009/42, C08L027/16, C08L027/18, C08L081/06
  • 专利详细信息:   CN110551318-A 10 Dec 2019 C08J-009/42 202004 Pages: 6 Chinese
  • 申请详细信息:   CN110551318-A CN10739223 12 Aug 2019
  • 优先权号:   CN10739223

▎ 摘  要

NOVELTY - Preparation of graphene-based heat and moisture exchange composite film involves (i) subjecting a natural flake graphite ethanol slurry or an expandable graphite ethanol slurry to a surfactant modification treatment by a condensation reflux method, (ii) ultrasonically treating the prepared slurry by supercritical carbon dioxide fluid method at 35-45 degrees C and pressure of 20-30 MPa for 20-26 hours and centrifuging the supernatant to obtain graphene quantum dots having particle size of 10-75 nm, (iii) immersing the microporous polyester film in the graphene quantum dot slurry, (iv) introducing the metal-organic framework precursor synthesis solution to the graphene quantum dot slurry, and depositing graphene quantum dots and metal organic framework in situ on the polyester microporous membrane after 24 hours, and (v) drying the polyester microporous membrane using 80-120 W microwave dryer for 10-20 minutes. USE - Preparation of graphene-based heat and moisture exchange composite film used as core material of membrane type heat exchange system. ADVANTAGE - The method produces composite film having excellent heat and moisture transmission properties, mechanical properties, and chemical stability. The heat exchange system has actively developed as an energy saving and environmentally protective device which effectively improves indoor air quality and reduces air-conditioning energy consumption.