• 专利标题:   Preparation of graphene-hard carbon composite material for preparing electrochemical capacitor, involves adding graphite oxide in water, dispersing, adding phenol and formaldehyde, polymerizing, and heating obtained composite material.
  • 专利号:   CN104064365-A
  • 发明人:   LIU D, WANG Y, ZHONG H, ZHOU M
  • 专利权人:   OCEANS KING LIGHTING SCI TECHNOLOGY CO, SHENZHEN OCEANS KING LIGHTING ENG CO LTD, SHENZHEN OCEANS KING LIGHTING SCI TECH
  • 国际专利分类:   H01G011/38, H01G011/84, H01G011/86
  • 专利详细信息:   CN104064365-A 24 Sep 2014 H01G-011/38 201501 Pages: 11 Chinese
  • 申请详细信息:   CN104064365-A CN10086367 18 Mar 2013
  • 优先权号:   CN10086367

▎ 摘  要

NOVELTY - Preparation of graphene-hard carbon composite material involves adding graphite oxide in water, ultrasonically dispersing, adjusting pH of obtained graphene oxide suspension to 2-5, adding phenol and formaldehyde to the graphene oxide suspension, stirring, heating such that polymerization reaction of phenol and formaldehyde is carried out, placing obtained graphene oxide and phenolic resin composite material in inert gas atmosphere, heating at rate of 5-25 degrees C/minute to 800-900 degrees C for 0.5-2 hours, and cooling. USE - Preparation of graphene-hard carbon composite material used for preparing electrochemical capacitor (all claimed). ADVANTAGE - The method enables preparation of graphene-hard carbon composite material with specific surface area of 800-1174 m2/g. DETAILED DESCRIPTION - Preparation of graphene-hard carbon composite material involves adding graphite oxide in water, ultrasonically dispersing, adjusting pH of obtained graphene oxide suspension to 2-5, adding phenol and formaldehyde to the graphene oxide suspension, stirring, heating such that polymerization reaction of phenol and formaldehyde is carried out, placing obtained graphene oxide and phenolic resin composite material in inert gas atmosphere, heating at rate of 5-25 degrees C/minute to 800-900 degrees C for 0.5-2 hours, and cooling. The mass ratio of graphene oxide and phenol is 5:0.5-3. The mass ratio of phenol and formaldehyde is 1.1-1.3:1. INDEPENDENT CLAIMS are included for the following: (1) electrochemical capacitor; and (2) preparation of electrochemical capacitor.