• 专利标题:   Preparation of graphene-loaded manganese oxide composite material involves mixing water and graphene oxide, adding zinc and manganese salts, stirring with sodium hydroxide, mixing with hydrochloric acid, drying, and heat-preserving.
  • 专利号:   CN107068411-A, CN107068411-B
  • 发明人:   CHEN Y, GU H, CHEN Z
  • 专利权人:   UNIV WUHAN SCI TECHNOLOGY, UNIV WUHAN SCI TECHNOLOGY
  • 国际专利分类:   B82Y030/00, H01G011/24, H01G011/36, H01G011/46, H01G011/86
  • 专利详细信息:   CN107068411-A 18 Aug 2017 H01G-011/24 201766 Pages: 7 Chinese
  • 申请详细信息:   CN107068411-A CN10349792 17 May 2017
  • 优先权号:   CN10349792

▎ 摘  要

NOVELTY - Preparation of graphene-loaded manganese oxide composite material comprises mixing water and graphene oxide and ultrasonically dispersing for 1-24 hours; mixing water, zinc nitrate and manganous sulfate and stirring; mixing with graphene oxide colloid; adding sodium hydroxide solution and hydrogen peroxide solution, stirring for 0.5-3 hours, filtering, and washing; and mixing with hydrochloric acid solution at ratio of 0.02-1:2000, stirring for 0.5-4 hours, filtering, washing, drying, and heat-preserving for 0.5-24 hours at 150-500 degrees C under inert gas or air condition. USE - Method for preparing graphene-loaded manganese oxide composite material (claimed). ADVANTAGE - The composite material has uniform shape and high electrochemical performance. DETAILED DESCRIPTION - Preparation of graphene-loaded manganese oxide composite material comprises mixing water and graphene oxide at mass ratio of 200-10000:1 and ultrasonically dispersing for 1-24 hours; mixing water, zinc nitrate and manganous sulfate at mass ratio of 700-70000:1-10:1 and stirring; mixing with graphene oxide colloid at mass ratio of 0.04-200:1; adding sodium hydroxide solution and hydrogen peroxide solution at mass ratio of 0.02-500:1:0-30, stirring for 0.5-3 hours, filtering, and washing, where manganese suspension concentration is 0.001-0.03 mol/L, concentration of sodium hydroxide solution is 0.01-10 mol/L, and concentration of hydrogen peroxide solution is 10-30 wt.%; and mixing with hydrochloric acid solution at ratio of 0.02-1:2000, stirring for 0.5-4 hours, filtering, washing, drying, and heat-preserving for 0.5-24 hours at 150-500 degrees C under inert gas or air condition.