• 专利标题:   Metal-solid acid double-site catalyst contains acid site and metal site double center, where acid center is sulfonated graphene with two-dimensional planar structure, and metal center has higher carbon-oxygen hydrogen-active metal ruthenium.
  • 专利号:   CN111054392-A
  • 发明人:   TAN J, CUI J, ZHAO Y
  • 专利权人:   UNIV SHANXI
  • 国际专利分类:   B01J027/02, C07D307/44
  • 专利详细信息:   CN111054392-A 24 Apr 2020 B01J-027/02 202041 Pages: 9 Chinese
  • 申请详细信息:   CN111054392-A CN11251076 09 Dec 2019
  • 优先权号:   CN11251076

▎ 摘  要

NOVELTY - A metal-solid acid double-site catalyst contains acid site and metal site double center. The acid center is sulfonated graphene with two-dimensional planar structure. The metal center has higher carbon-oxygen hydrogen-active metal ruthenium. USE - Metal-solid acid double-site catalyst. ADVANTAGE - The catalyst exhibits excellent catalytic performance in direct preparation of furfuryl alcohol by one-step method of catalyzing xylose through dehydration-hydrogenation. The reaction is simple. The catalyst can be recycled. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the metal-solid acid dual-site catalyst comprises subjecting graphene to sulfonation modification to give graphene rich protonic acid sites on two-dimensional plane. The metal ruthenium with high catalytic activity and good stability in water phase supported on surface of sulfonated graphene is metal hydrogenation site.