• 专利标题:   Preparation of three-dimensional porous heteroatom-doped graphene used for preparing combined membrane electrode for e.g. fuel battery, by ultrasonically dispersing graphene oxide, heteroatom precursor, noble metal salt and templating agent.
  • 专利号:   CN104475172-A, CN104475172-B
  • 发明人:   QIAO J, WU M, XU P, ZHOU X, LI H, LI X, LIU Y, ZHANG J, ZHANG X
  • 专利权人:   UNIV DONGHUA, STATE GRID SHANGHAI MUNICIPAL ELECTRIC, UNIV SHANGHAI
  • 国际专利分类:   B01J021/18, B01J023/745, B01J027/02, B01J027/185, B01J027/24, B01J037/16
  • 专利详细信息:   CN104475172-A 01 Apr 2015 B01J-037/16 201540 Pages: 9 Chinese
  • 申请详细信息:   CN104475172-A CN10674187 21 Nov 2014
  • 优先权号:   CN10674187

▎ 摘  要

NOVELTY - Preparation of three-dimensional porous heteroatom-doped graphene comprises ultrasonically dispersing graphene oxide, heteroatom precursor, noble metal salt and templating agent in solvent, heating, stirring, drying to obtain precursor, placing in quartz boat, baking under reducing inert gas atmosphere at 600-1000 degrees C at heating speed of 5-25 degrees C/minute for 1-3 hours, cooling to obtain solid, treating with mixed liquid of hydrofluoric acid and hydrochloric acid for 12-24 hours, washing with deionized water, drying, and baking under reducing inert gas atmosphere at 600-1000 degrees C for 1-3 hours. USE - Method for preparing three-dimensional porous heteroatom-doped graphene used for preparing combined membrane electrode (claimed) for fuel battery, metal-air battery and supercapacitor. ADVANTAGE - The graphene has high specific surface area. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for production of combined membrane electrode comprising ultrasonically dispersing three-dimensional porous heteroatom-doped graphene with dispersant to obtain catalyst, transferring to glassy carbon electrode and drying at room temperature.