• 专利标题:   Producing graphene layers on a substrate, comprises applying paste comprising graphene nanoplatelets mixed with organic vehicle in form of polymethyl methacrylate solution and annealing paste on the substrate.
  • 专利号:   EP2570462-A1, PL396373-A1, PL222519-B1, EP2570462-B1
  • 发明人:   JAKUBOWSKA M, MONIKA A, SOMA M, M?O?NIAK A, MLOZNIAK A, SLOMA M, JAKUBOWSKA M G
  • 专利权人:   MATERIALOW ELEKTRONICZNYCH TECHNOLOGY, MATERIALOW ELEKTRONICZNYCH TECHNOLOGY
  • 国际专利分类:   B82Y030/00, C01B031/00, C09D011/00, H01M004/00, C01B031/04, C08K003/04, C09D005/24, C08L033/12, C08L069/00, C09D011/033, C09D011/037, C09D011/52
  • 专利详细信息:   EP2570462-A1 20 Mar 2013 C09D-011/00 201322 Pages: 20 English
  • 申请详细信息:   EP2570462-A1 EP184435 14 Sep 2012
  • 优先权号:   PL396373

▎ 摘  要

NOVELTY - Producing graphene layers on a substrate, comprises: applying a paste comprising 0.5-15 wt.% of graphene nanoplatelets mixed with an organic vehicle in the form of a polymethyl methacrylate solution in Butyl carbitol (RTM: Diethylene glycol butyl ether) acetate with a concentration of 2-10 wt.% or in the form of a polycarbonate solution in Butyl carbitol (RTM: Diethylene glycol butyl ether) acetate with a concentration of 5-12 wt.% on the substrate by the screen printing method; and annealing the paste applied on the substrate at 100-500 degrees C. USE - The method is useful for producing graphene layers on a substrate (claimed) which is used in electronics and microelectronics to produce transparent conductive layers which form transparent electrodes in display devices, electrodes in lithium-ion batteries, electrodes with developed active surface in electrolytic capacitors including supercapacitors, field-effect transistors, chemical sensors and biological substances featuring high sensitivity, selectivity and speed of reaction including gas detectors, resistive layers for electronics, and resistive thermal and electromechanical sensors. ADVANTAGE - The method: utilizes the paste which does not allow resistive or conductive graphene layers; provides graphene layers even on surfaces of temperature-sensitive substrates including aluminum, plastic materials (films), fabrics and paper; is quick and inexpensive; and quickly coats large surfaces. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for a paste having graphene nanoplatelets and an organic vehicle, comprising 0.5-15 wt.%, preferably 5-8 wt.% of graphene nanoplatelets, an organic vehicle in the form of a polymethyl methacrylate solution in Butyl carbitol (RTM: Diethylene glycol butyl ether) acetate with the concentration of 2-10 wt.%, preferably 8 wt.% or a vehicle in the form of a polycarbonate solution in Butyl carbitol (RTM: Diethylene glycol butyl ether) acetate with the concentration of 5-12 wt.%, preferably 10 wt.%, or possibly additives which improve dispersion, additives which improve the rheology of the paste and agents which reduce surface tension, facilitate de-agglomeration and prevent re-agglomeration and sedimentation of the filler.