• 专利标题:   Catalytic etherification of glycerol to prepare glycerol ether involves subjecting glycerol and isobutylene to catalytic reaction in presence of sulfonated graphene acid catalyst, and performing extraction and separation.
  • 专利号:   CN103910612-A, CN103910612-B
  • 发明人:   WANG Y, ZHANG S, ZHOU J
  • 专利权人:   UNIV DALIAN
  • 国际专利分类:   C07C041/06, C07C043/10, C07C043/13
  • 专利详细信息:   CN103910612-A 09 Jul 2014 C07C-043/10 201465 Pages: 7 Chinese
  • 申请详细信息:   CN103910612-A CN10080975 06 Mar 2014
  • 优先权号:   CN10080975

▎ 摘  要

NOVELTY - Catalytic etherification of glycerol to prepare glycerol ether is carried out by subjecting glycerol and isobutylene to catalytic reaction in presence of acid catalyst 40-110 degrees C to generate glycerol ether, glycerol diether and triglyceride ether; and performing extraction and separation to remove unreacted glycerol and catalyst and obtain glycerol ether product. Mole ratio of glycerol and isobutylene is 1:1-1:100. The acid catalyst is sulfonated graphene catalyst. USE - Method for catalytic etherification of glycerol to prepare glycerol ether (claimed). ADVANTAGE - The method has separation step that does not introduce other reagent material and can remove impurities without using high energy consumption. The entire process is energy-saving and green and environment-friendly.