• 专利标题:   Preparing quaternized haloamine-modified graphene oxide antibacterial nanoparticles by polymerizing graphene oxide by 4-vinylpyridine, grafting it with 3-bromopropyl-5,5-dimethylhydantoin by quaternization reaction, and chlorinating it.
  • 专利号:   CN112970761-A, CN112970761-B
  • 发明人:   XIAO L, AO Y, BU D, CHENG C, FENG H, WANG R, ZHANG J
  • 专利权人:   UNIV CHANGCHUN TECHNOLOGY
  • 国际专利分类:   A01N043/50, A01P001/00, B82Y030/00, B82Y040/00, C07D401/14, C08F226/06, C08F292/00, C08F008/20, C08F008/30
  • 专利详细信息:   CN112970761-A 18 Jun 2021 A01N-043/50 202163 Pages: 10 Chinese
  • 申请详细信息:   CN112970761-A CN10147095 03 Feb 2021
  • 优先权号:   CN10147095

▎ 摘  要

NOVELTY - Preparation method of quaternized haloamine-modified graphene oxide antibacterial nanoparticles, involves (a) using 1,3-dibromopropane, anhydrous potassium carbonate, and 5,5-dimethyl hydantoin to prepare 3-bromopropyl-5,5-dimethyl hydantoin, (b) using 4-vinylpyridine to polymerize graphene oxide in situ under the catalysis of potassium persulfate to obtain 4-vinylpyridine modified graphene oxide, (c) using the 3-bromopropyl-5,5-dimethylhydantoin obtained in step (a) to graft the 4-vinylpyridine-modified graphene oxide obtained in step (b) through quaternization reaction to obtain quaternized haloamine modified graphene oxide, and (d) chlorinating the quaternized haloamine-modified graphene oxide obtained in step (c) with an aqueous sodium hypochlorite solution to obtain quaternized haloamine-modified graphene oxide antibacterial nanoparticles. USE - The method is used for preparation of quaternized haloamine-modified graphene oxide antibacterial nanoparticles (claimed). ADVANTAGE - The antibacterial nanoparticles has excellent antibacterial effect, can be recycled through the sterilization and chlorination process, and simultaneously has the functions of contact sterilization and release sterilization.