• 专利标题:   Preparing deep metastable emulsion (DME) of two-dimensional material (2DM) for e.g., producing inks, by forming three-phase system having DME middle phase comprising 2DM by dispersing 2DM in various solvents having different miscibilities.
  • 专利号:   EP3848420-A1, WO2021140139-A1, EP4087901-A1
  • 发明人:   ABDOLHOSSEINZADEH S, HEIER J, NUEESCH F
  • 专利权人:   EMPA EIDGENOESSISCHE MATERIALPRUEFUNGS, EMPA EIDGENOESSISCHE MATERIALPRUEFUNGS
  • 国际专利分类:   C01B032/19, C09D011/52, C09D005/02, C09D005/24, C09D007/40, H01B001/24
  • 专利详细信息:   EP3848420-A1 14 Jul 2021 C09D-005/02 202162 Pages: 25 English
  • 申请详细信息:   EP3848420-A1 EP150937 09 Jan 2020
  • 优先权号:   EP150937

▎ 摘  要

NOVELTY - A deep metastable emulsion (DME) of two-dimensional material (2DM) is prepared by (S1) dispersing 2DM in a solvent X which comprises water or is miscible in water; (S2.1) adding and mixing a further solvent Y which is immiscible in solvent Z and miscible in solvent X, or (S2.2) adding and mixing a further solvent Y, where solvents X and/or Y comprise further solvent T, which is miscible in solvent X and solvent Y, and solvent Y is immiscible in water and immiscible in solvent X, but where solvent Y in combination with solvent T is miscible in solvent X; and (S3) adding and mixing solvent Z if solvent X does not comprise or does not comprise enough solvent Z for DME formation. Composition resulting from step (S2.1), (S2.2), or (S3) forms a three-phase system having a DME middle phase comprising the 2DM; and DME middle phase remains stable at room temperature and atmospheric pressure for greater than or equal to 1 week. USE - Preparation of deep metastable emulsion (DME) of two-dimensional material (2DM) and sterically stabilized suspension (SSS) of 2DM for production of inks particularly for printed electronics, three-dimensional (3D) printing inks, electronic devices, structural composites, coatings, paintings, conductive electrodes, batteries, supercapacitors, solar cells, fuel cells, detectors, sensors, drug delivery devices, thermal conductors, thermal barriers, and microwave shields, and for production of electronic devices, particularly electronic devices comprising conductors, semiconductors, or insulators made from DME and/or SSS (all claimed). ADVANTAGE - The methods and products can be reproduced for essentially all 2DMs and do not require any specific solvent system for DME and/or SSS formation and stability. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: (1) DME of 2DM; and (2) sterically stabilized suspension (SSS) of 2DM.