• 专利标题:   Preparing graphene-coated metal-doped composite anode material comprises e.g. rapidly heat-treating graphite oxide powder, mixing metal-graphene composite material and anode material, sintering and sieving.
  • 专利号:   CN107994219-A
  • 发明人:   XIONG W, ISAO K, SHANG S
  • 专利权人:   SOUNDON NEW ENERGY TECHNOLOGY CO LTD
  • 国际专利分类:   H01M004/36, H01M004/485, H01M004/505, H01M004/525, H01M004/587, H01M004/62, H01M010/0525
  • 专利详细信息:   CN107994219-A 04 May 2018 H01M-004/36 201839 Pages: 9 Chinese
  • 申请详细信息:   CN107994219-A CN11203352 27 Nov 2017
  • 优先权号:   CN11203352

▎ 摘  要

NOVELTY - Preparing graphene-coated metal-doped composite anode material comprises e.g. (i) rapidly heat-treating graphite oxide powder in air atmosphere, then adding concentrated acid and potassium permanganate to obtain exfoliated graphite, dispersing exfoliated graphite in deionized water and placing under ultrasonic conditions for 2-3 hours to obtain graphene oxide suspension, (ii) adding metal salt into organic solution and dissolving to obtain metal salt/solution system, (iii) mixing graphene oxide suspension with the metal salt/solution system, and then stirring at 150 degrees C for 4 hours, suction filtering to obtain metal-graphene composite precursor metal material, washing metal-graphene composite precursor with distilled water and absolute ethanol at pH 7 and drying at 110 degrees C for 1 hour to obtain metal-graphene composite material, and (iv) mixing metal-graphene composite material and anode material, and sintering by multi-stage constant temperature method, and crushing product and sieving. USE - The method is useful for preparing graphene-coated metal-doped composite anode material. ADVANTAGE - The anode material has synergistic effect. DETAILED DESCRIPTION - Preparing graphene-coated metal-doped composite anode material comprises (i) rapidly heat-treating graphite oxide powder in air atmosphere, then adding concentrated acid and potassium permanganate to obtain exfoliated graphite, dispersing exfoliated graphite in deionized water and placing under ultrasonic conditions for 2-3 hours to obtain graphene oxide suspension, (ii) adding metal salt into organic solution and dissolving to obtain metal salt/solution system, (iii) mixing graphene oxide suspension with the metal salt/solution system in a certain ratio, stirring at 80 degrees C for 6 hours, and then stirring at 150 degrees C for 4 hours, suction filtering to obtain metal-graphene composite precursor metal material, washing metal-graphene composite precursor with distilled water and absolute ethanol at pH 7 and drying at 110 degrees C for 1 hour to obtain metal-graphene composite material, and (iv) mixing metal-graphene composite material and anode material in a certain mass ratio, and sintering by multi-stage constant temperature method, and crushing product and sieving. An INDEPENDENT CLAIM is also included for graphene-coated metal-doped composite anode material obtained by above method.