• 专利标题:   Reduction of graphene oxide to prepare graphene, involves dispersing graphene oxide in water, adding sodium-tellurium hydride solution, reacting, filtering, washing solid with sodium borohydride aqueous solution and water, and drying.
  • 专利号:   CN102795622-A
  • 发明人:   WANG C, ZHANG Y, HAN C, SUN L, LIU B
  • 专利权人:   UNIV HEILONGJIANG
  • 国际专利分类:   C01B031/04
  • 专利详细信息:   CN102795622-A 28 Nov 2012 C01B-031/04 201334 Pages: 9 Chinese
  • 申请详细信息:   CN102795622-A CN10336379 12 Sep 2012
  • 优先权号:   CN10336379

▎ 摘  要

NOVELTY - Graphene oxide is ultrasonically dispersed in deionized water at 80-100 KHz for 20-40 minutes, to obtain a uniform graphene oxide solution with a concentration of 4-8 mg/L. A sodium-tellurium hydride solution is added, stirred at 200-250 rpm, reacted for 1-3 hours, filtered, and separated to obtain a solid. The solid is washed with sodium borohydride aqueous solution 21 times and deionized water 5 times, and filtered. The obtained solid is washed, dried at 40-50 degrees C for 9-11 hours, and ground to obtain graphene powder. USE - Reduction of graphene oxide to prepare graphene. ADVANTAGE - The method enables simple, easy, economical, quick and nontoxic reduction of graphene oxide to graphene, by eliminating the usage of hydrazine hydrate and other toxic catalyst, under mild conditions. No special equipment is required. The obtained graphene has high quality. DETAILED DESCRIPTION - Graphene oxide is ultrasonically dispersed in deionized water at 80-100 KHz for 20-40 minutes, to obtain a uniform graphene oxide solution with a concentration of 4-8 mg/L. A sodium-tellurium hydride solution is added, stirred at 200-250 rpm, reacted for 1-3 hours, filtered, and separated to obtain a solid. The solid is washed with sodium borohydride aqueous solution 21 times and deionized water 5 times, and filtered. The obtained solid is washed, dried at 40-50 degrees C for 9-11 hours, and ground to obtain graphene powder. The mass ratio of sodium-tellurium hydride aqueous solution and graphene oxide aqueous solution is (2.9-6.9):1.