• 专利标题:   Preparation of composite modified electrode material for electrochemically extracting lithium in Salt Lake, involves mixing solutions comprising lithium source and graphene oxide, and titanium source, acetic acid and ethanol, and modifying using dopamine.
  • 专利号:   CN113278820-A, CN113278820-B
  • 发明人:   HE L, ZHAO Z, XU W, LIU X, CHEN X
  • 专利权人:   UNIV CENT SOUTH
  • 国际专利分类:   C22B026/12, C22B003/02, C22B003/42, H01M004/139
  • 专利详细信息:   CN113278820-A 20 Aug 2021 C22B-026/12 202179 Pages: 10 Chinese
  • 申请详细信息:   CN113278820-A CN10555922 21 May 2021
  • 优先权号:   CN10555922

▎ 摘  要

NOVELTY - Preparation of composite modified electrode material involves adding a lithium source and graphene oxide into 50 %mass ethanol solution, stirring to obtain a lithium source/graphene oxide mixed solution containing 0.2-1 g/L lithium and 1-3 g/L graphene oxide, adding lithium extracting electrode active material, obtaining a mixed solution (A), dissolving titanium source in a mixed solution of acetic acid and absolute ethanol to obtain a mixed solution (B), mixing the mixed solution (A) and the mixed solution (B) to form a gel, heating to 70-85 degrees C for 1-3 hours, drying, roasting for 10 hours at 550 degrees C to obtain a graphene oxide/titanium lithium-ion sieve coated modified electrode active material, mixing with dopamine solution in the liquid-solid mass ratio of 5-10:1, carrying out poly-dopamine coating modification, filtering, washing, and drying. USE - Preparation of composite modified electrode material for electrochemically extracting lithium in Salt Lake (all claimed). ADVANTAGE - The method enables simple preparation of electrode material having improved selectivity, high extraction rate, and high efficiency. DETAILED DESCRIPTION - Preparation of composite modified electrode material involves adding a lithium source and graphene oxide into 50 %mass ethanol solution, stirring to obtain a lithium source/graphene oxide mixed solution containing 0.2-1 g/L lithium and 1-3 g/L graphene oxide, adding lithium extracting electrode active material, obtaining a mixed solution (A), dissolving titanium source in a mixed solution of acetic acid and absolute ethanol to obtain a mixed solution (B), mixing the mixed solution (A) and the mixed solution (B) to form a gel, heating to 70-85 degrees C for 1-3 hours, drying, roasting for 10 hours at 550 degrees C to obtain a graphene oxide/titanium lithium-ion sieve coated modified electrode active material, mixing with dopamine solution in the liquid-solid mass ratio of 5-10:1, carrying out poly-dopamine coating modification, filtering, washing, and drying. The molar ratio of the electrode active material for extracting lithium and lithium in the lithium source is 5-20:1 and the molar ratio of lithium in the lithium source and the titanium in the titanium source is 2:1. INDEPENDENT CLAIMS are included for the following: (1) composite modified electrode active material for extracting lithium; (2) electrode for electrochemically extracting lithium comprising the composite modified electrode active material; and (3) preparation of the electrode for electrochemically extracting lithium, which involves pulping composite modified electrode active material, 10-15 %mass conductive agent, 10-30 %mass pore-forming agent, 8-15 %mass polyvinylidene fluoride, and 150-200 %mass N-methylpyrrolidone to form a slurry, uniformly coating the slurry on a current collector, drying, and soaking in water.